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Note that the dimensionless group (DΔE* /r*cl2v, r*clf*/ko)β can also be written as (RgTD/Fvr*el 2)(FΔE*/RgT, r*clf*/k0) β In the latter group, the first term, R gTD/Fvr*el2, was introduced by Aoki et al.32 to study linear sweep voltammetry at small disc electrodes and, since then, has often been used to study various linear sweep voltammetry and CV cases. Because in the present work the group (FAE*/RgT) is constant for all simulations, the results presented in this analysis can be readily interpreted with respect to RgTD/Fvr*el 2
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β used in the present work reflects the fact that the voltage excitation studied herein is a superposition of a "slow" ramp with a "fast" large-amplitude/high-frequency harmonic oscillation.
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