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Reductive coupling of carbonyl compounds based on the combination of zinc and chlorosilane, see: a
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22
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38149068041
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The general procedure for the reductive coupling of 1 and the physical data of 1 and 2 are available as Supporting Information on the CSJ Journal Web site, http://www.csj. jp/journals/chem-lett/index.html.
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The general procedure for the reductive coupling of 1 and the physical data of 1 and 2 are available as Supporting Information on the CSJ Journal Web site, http://www.csj. jp/journals/chem-lett/index.html.
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23
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38149034192
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1H NMR.
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1H NMR.
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24
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38149053861
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References are cited in Ref. 1.
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References are cited in Ref. 1.
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25
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38149060588
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In the treatment of la with zinc and tetrachlorosilane for 1 h instead of 5h, 2a (dl/meso, 72/28) was obtained in 18% yield along with 3a 5% yield
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In the treatment of la with zinc and tetrachlorosilane for 1 h instead of 5h, 2a (dl/meso = 72/28) was obtained in 18% yield along with 3a (5% yield).
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26
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38149002770
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Acetals were prepared according to literatures, see: a
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Acetals were prepared according to literatures, see: a) D. P. Roelofsen, H. van Bekkum, Synthesis 2002, 419.
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Synthesis
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Roelofsen, D.P.1
van Bekkum, H.2
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27
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0037047512
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b) R. Gopinath, S. J. Haque, B. K. Patel, J. Org. Chem. 2002, 67, 5842.
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Gopinath, R.1
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a) Y. Zhu, Y. Pan, S. Huang, Heterocycles 2005, 65, 133.
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b) Y. Zhu, Y. Pan, S. Huang, Synth. Commun. 2005, 34, 3167.
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