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We evaluated all σ(c) curves with the Langmuir, the Frumkin, and the reorientation models. Moreover, we carried out a model-independent fitting of the curves with second-order polynomials. It turned out that the a(c) curves of β-C12G2 and C12E3I 1, are best described with the Frumkin model, whereas the σ(C) curve of C12E6 could be described with all models and a polynomial. The simple reason for this insensitivity of the C12E 6 data is the fact that surface tension data at very low concentrations (i.e, at concentrations where the differences in the models are most visible) are not available and thus it is not clear which model would describe our data best. However, fitting the σ(c) curve of C 12E6 with all three models as well as with the polynomial and comparing the resulting Γ(c) curves with those of β-C 12G2
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1).
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23
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1 in Table 1 can only be considered as rough estimates.
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1 in Table 1 can only be considered as rough estimates.
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25
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