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m device is increased when employing the electrode modified with the clusters for a longer duration of the applied voltage; the maximum IPCE value is obtained when the electrophoretic deposition is complete (2 min).
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m device is increased when employing the electrode modified with the clusters for a longer duration of the applied voltage; the maximum IPCE value is obtained when the electrophoretic deposition is complete (2 min).
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11,16-19]
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X-ray crystal structure data for 3,5-OMeTPP·2C 60·toluene: C179H54N4O 8, monoclinic, crystal size, 0.30×0.20×0.20 mm. space group, P21/c (no. 14, a, 26.214(3, b, 16.7238(17, c, 26.148(3) Å, β, 116.382(4)°, V= 10269.3(19) Å3 Z, 4. ρcalcd, 1.545 g cm-3, 2θmax, 51°, T, 93.1 K, μ, 0.095 mm-1, Tmin, 0.877, Tmax, 0.981, 19081 measured reflections. 15904 independent reflections, 683 refined parameters. wR2, 0.3138, R, 0.1227 (1>2.00σI, GOF, 1.071, max/min residual electron density, 1.16/-1.02 eÅ3. CCDC-143512 contains the supplementary crystallography data for this compound
-
3. CCDC-143512 contains the supplementary crystallography data for this compound.
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We could not obtain reliable nanosecond time-resolved transient spectra of the composite clusters in the mixed solvent because of a poor signal-to-noise ratio and the instability of the samples under the experimental conditions
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In the Supporting Information the following is available: Absorption spectra of H2P and C60 in toluene (S1, lowest energy conformation of H2P (S2, dependence of [H 2P]/AbsCT on the reciprocal concentration of C 60 (S3, solid-state 13C NMR spectra of the clusters (S4, optical microscopic images of electrodes (S5, photocurrent action spectra as a function of the initial C60 concentrations (S6, ORTEP diagram of 3,5-OMeTPP·2C60·toluene (S7, and diffuse reflectance absorption spectrum of ground powder of single crystals of 3,5-OMeTPP·2C60toluene (S8, and fluorescence spectra of electrodes S9
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60toluene (S8), and fluorescence spectra of electrodes (S9).
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