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In addition, in the transition metal MPcs examined by Craciun et al, the chemical potential must be in equilibrium with a partly filled metal d-level. Strongly localized, this orbital should possess a much larger onsite Coulomb repulsion and must constitute a nontrivial magnetic complication, which is absent in MgPc. The interplay of metallic conduction in the LUMO with the localized d-level will no doubt generate future interest in transition metal MPcs as mixed valent systems with either double exchange or Kondo intramolecular couplings
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We note that besides the distortion induced b3g↑-b 2g↑ splitting of 126 meV, there is also an exchange splitting of 149 meV for the b3g level and of 49 meV for the b2g level. There are also spin splittings of smaller magnitude of all other occupied states
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