Reactivity of Fe/M (M = Ce, Mn, Al) oxide-hydroxides for hydrosulfide removal in anoxic and oxic solutions

Separation and Purification Technology

Volumn 59, Issue 2, 2008, Pages 151-163

  Petre, Catalin F ^a   Larachi, Faïçal ^a  

^a UNIVERSITÉ LAVAL   (Canada)

Author keywords

Aluminum; Cerium; Dissolved oxygen; Hydrosulfide oxidation; Iron; Manganese; Polysulfides; Pulp and paper industry

Indexed keywords

CHEMICAL REACTIVITY; DISSOLVED OXYGEN; HYDROGEN INORGANIC COMPOUNDS; PAPER AND PULP INDUSTRY;

ANOXIC SOLUTIONS; BATCH SLURRY REACTORS; HYDROSULFIDE OXIDATION; OXIC SOLUTIONS;

IRON COMPOUNDS;

CHEMICAL REACTIONS; DISSOLVED OXYGEN; HYDROGEN COMPOUNDS; IRON COMPOUNDS; PAPER INDUSTRY;

EID: 38049105393     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2007.06.002     Document Type: Article

References (30)

1. 2S removal from pulp and paper emissions. Ind. Eng. Chem. Res. 44 (2005) 9391-9397
2. Millero F.J. The thermodynamics and kinetics of the hydrogen-sulfide system in natural-waters. Mar. Chem. 45 (1986) 121-147
3. Pyzik A.J., and Sommer S.E. Sedimentary iron monosulfides-kinetics and mechanism of formation. Geochim. Cosmochim. Acta 45 (1981) 687-698
4. dos Santos Afonso M., and Stumm W. Reductive dissolution of iron(III) (hydr)oxides by hydrogen-sulfide. Langmuir 8 (1992) 1671-1675
5. 2S with lepidocrocite. Environ. Sci. Technol. 262 (1992) 2408-2413
6. Yao W., and Millero F.J. Oxidation of hydrogen sulfide by hydrous Fe(III) oxides in seawater. Marine Chem. 52 (1996) 1-16
7. Poulton S.W., Krom M.D., and Raiswell R. Revised scheme for the reactivity of iron (oxyhydr)oxide minerals towards dissolved sulfide. Geochim. Cosmochim. Acta 68 (2004) 3703-3715
8. Petre C.F., and Larachi F. Reaction between hydrosulfide and iron/cerium (hydr)oxide: hydrosulfide oxidation and iron dissolution kinetics. Top. Catal. 37 (2006) 97-106
9. Chen H., Sayari A., Adnot A., and Larachi F. Composition-activity effects of Mn-Ce-O composites on phenol catalytic wet oxidation. Appl. Catal. B: Environ. 32 (2001) 195-204
10. Trovarelli A. Catalysis by Ceria and Related Materials (2002), Imperial College Press, London
11. Burdige D.J., and Nealson K.H. Chemical and microbiological studies of sulfide-mediated manganese reduction. Geomicrobiol. J. 4 (1986) 361-387
12. 2 in seawater. Geochim. Cosmochim. Acta 57 (1993) 3359-3365
13. Yao W., and Millero F.J. Geochemical transformations of sedimentary sulfur. In: Vairavamurthy M.A., and Schoonen M.A.A. (Eds). ACS Symposium Series 612 (1995), American Chemical Society, Washington, DC
14. Herszage J., and dos Santos Afonso M. Mechanism of hydrogen sulfide oxidation by manganese(IV) oxide in aqueous solutions. Langmuir 19 (2003) 9684-9692
15. Pourbaix M. Atlas D'équilibres Électrochimiques (1963), Gauthier-Villars & Cie Eds, Paris
16. Imamura S., and Doi A. Wet oxidation of ammonia catalyzed by cerium-based composite oxides. Ind. Eng. Chem. Prod. Res. Dev. 24 (1985) 75-85
17. Petre C.F., and Larachi F. Capillary electrophoretic separation of inorganic sulfur-sulfide, polysulfides, and sulfur-oxygen species. J. Sep. Sci. 29 (2006) 144-152
18. Schulze D.G. The influence of aluminum on iron-oxides. 8. Unit-cell dimensions of Al-substituted goethites and estimation of Al from them. Clays Clay Miner. 32 (1984) 36-44
19. Schulze D.G., and Schwertmann U. The influence of aluminum on iron-oxides. 13. Properties of goethites synthesized in 0.3-M KOH at 25 °C. Clay Miner. 22 (1987) 83-92
20. Goethite mineral data, Web mineralogy database, http://webmineral.com/data/Goethite.shtml.
21. Frost R.L., Ding Z., and Ruan H.D. Thermal analysis of goethite-relevance to Australian indigenous art. J. Therm. Anal. Calor. 71 (2003) 783-797
22. Balek V., and Subrt J. Thermal-behavior of iron(III) oxide-hydroxides. Pure Appl. Chem. 67 (1995) 1839-1842
23. Everett D.H. IUPAC manual of symbols and terminology. Pure Appl. Chem. 31 (1972) 578
24. Steudel R. Mechanism for the formation of elemental sulfur from aqueous sulfide in chemical and microbiological desulfurization processes. Ind. Eng. Chem. Res. 35 (1996) 1417-1423
25. 2. Environ. Sci. Technol. 6 (1972) 529-537
26. Kotronarou A., and Hoffmann M.R. Catalytic autoxidation of hydrogen-sulfide in waste-water. Environ. Sci. Technol. 25 (1991) 1153-1160
27. Santana-Casiano J.M., Gonzales-Davila M., and Millero F.J. Oxidation of nanomolar levels of Fe(II) with oxygen in natural waters. Environ. Sci. Technol. 39 (2005) 2073-2079
28. Schippers A., Neretin L.N., Lavik G., Leipe T., and Pollehne F. Manganese(II) oxidation driven by lateral oxygen intrusions in the western Black Sea. Geochim. Cosmochim. Acta 69 (2005) 2241-2252
29. Widdel F., Schnell S., Heising S., Ehrenreich A., Assmus B., and Schink B. Ferrous iron oxidation by anoxygenic phototrophic bacteria. Nature 362 (1993) 834-836
30. Doré M. Chimie des Oxydants et Traitement des eaux (1989), Techniques et documentation, Lavoisier, Paris