Spin-density distribution of the carotenoid triplet state in the peridinin-chlorophyll-protein antenna. A Q-band pulse electron-nuclear double resonance and density functional theory study

Journal of the American Chemical Society

Volumn 129, Issue 50, 2007, Pages 15442-15443

  Niklas, Jens ^a   Schulte, Tim ^b   Prakash, Shipra ^a   Van Gastel, Maurice ^a   Hofmann, Eckhard ^b   Lubitz, Wolfgang ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^b RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CAROTENOID; CHLOROPHYLL; MONOMER; PERIDININ; UNCLASSIFIED DRUG;

ARTICLE; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; DINOFLAGELLATE; ELECTRON; ELECTRON NUCLEAR DOUBLE RESONANCE; ELECTRON SPIN RESONANCE; ENERGY TRANSFER; ILLUMINATION; LIGHT HARVESTING SYSTEM; NONHUMAN; PHOTOCHEMISTRY; PROTEIN FOLDING; SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

CAROTENOIDS; CHLOROPHYLL; CRYSTALLOGRAPHY, X-RAY; ELECTRON SPIN RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; NUCLEAR MAGNETIC RESONANCE, BIOMOLECULAR; PROTEINS;

EID: 37849032090     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja077225v     Document Type: Article

References (23)

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21. A preliminary internal report on Mims ENDOR at X-band of triplet peridinin in MFPCP has been given by S. Parrish and A. Angerhofer (NHMFL Annual Research Review 1999, pp. 22-23).
22. 1H ENDOR spectra of MFPCP are very similar (data not shown).
23. 1H hyperfine tensors were calculated with the ORCA program package. Further details are provided in the Supporting Information.