Phase equilibria and thermodynamics of binary copper systems with 3d-metals. VII. Concentration-temperature dependences of the thermodynamic functions of mixing for liquid alloys of copper and transition metals

Powder Metallurgy and Metal Ceramics

Volumn 46, Issue 11-12, 2007, Pages 565-581

  Turchanin, M A ^a  

^a DONBASS STATE ENGINEERING ACADEMY   (Ukraine)

Author keywords

Copper based alloys; Excess heat capacity of liquid alloys; Excess thermodynamic functions of mixing; Temperature concentration dependence; Thermodynamic modeling; Thermodynamics

Indexed keywords

COPPER-BASED ALLOYS; EXCESS HEAT CAPACITY OF LIQUID ALLOYS; EXCESS THERMODYNAMIC FUNCTIONS OF MIXING; TEMPERATURE-CONCENTRATION DEPENDENCE; THERMODYNAMIC MODELING;

ENTHALPY; MATHEMATICAL MODELS; PHASE EQUILIBRIA; SPECIFIC HEAT; TRANSITION METALS;

COPPER ALLOYS;

EID: 37749040952     PISSN: 10681302     EISSN: 15739066     Source Type: Journal    
DOI: 10.1007/s11106-007-0087-4     Document Type: Article

References (64)

1. M. A. Turchanin, "Phase equilibria and thermodynamics of binary copper systems with 3d-metals. I. The copper-scandium system," Powder Metall. Met. Ceram., 45, No. 3-4, 143-152 (2006).
2. M. A. Turchanin, "Phase equilibria and thermodynamics of binary copper systems with 3d-metals. II. The copper-vanadium system," Powder Metall. Met. Ceram., 45, No. 5-6, 272-278 (2006).
3. M. A. Turchanin, "Phase equilibria and thermodynamics of binary copper systems with 3d-metals. III. Copper-chromium system," Powder Metall. Met. Ceram., 45, No. 9-10, 457-467 (2006).
4. M. A. Turchanin, P. G. Agraval, and A. R. Abdulov, "Phase equilibria and thermodynamics of binary copper systems with 3d-metals. IV. Copper-manganese system," Powder Metall. Met. Ceram., 45, No. 11-12, 569-581 (2006).
5. M. A. Turchanin and P. G. Agraval, "Thermodynamics of liquid alloys, and stable and metastable phase equilibria in the copper-iron system," Powder Metall. Met. Ceram., 40, No. 7-8, 337-353 (2001).
6. M. A. Turchanin and P. G. Agraval, "Phase equilibria and thermodynamics of binary copper systems with 3d metals. V. Copper-cobalt system," Powder Metall. Met. Ceram., 46, No. 1-2, 77-89 (2007).
7. M. A. Turchanin, P. G. Agraval, and A. R. Abdulov, "Phase equilibria and thermodynamics of binary copper systems with 3d-metals. VI. Copper-nickel system," Powder Metall. Met. Ceram., 46, No. 9-10, 467-477 (2007).
8. M. A. Turchanin, P. G. Agraval, A. N. Fesenko, and A. R. Abdulov, "Thermodynamics of liquid alloys and metastable phase transformations in the copper-titanium system," Powder Metall. Met. Ceram., 44, No. 5-6, 259-270 (2005).
9. T. B. Massalski, H. Okamoto, P. R. Subramanian, and L. Kacprzak (eds.), Binary Alloys Phase Diagrams, 2nd ed., ASM International, The Materials Information Society (1990).
10. M. A. Turchanin, S. V. Porokhnya, and I. V. Nikolaenko, "Calorimetric study of heats of formation of liquid copper-scandium alloys," Rasplavy, No. 5, 9-12 (1996).
11. S. Watanabe and O. J. Kleppa, "Thermochemistry alloys of transition metals: Part IV. Alloys of copper with scandium, yttrium, lanthanum, and lutetium," Metall. Trans. B, 15, No. 2, 357-368 (1984).
12. M. A. Turchanin and S. V. Porokhnya, "Enthalpy of formation of liquid alloys of copper with titanium and zirconium," Rasplavy, No. 5, 29-32 (1995).
13. K. T. Jacob, S. Priya, and Y. Waseda, "A thermodynamic study of liquid Cu-Cr alloys and metastable liquid immiscibility," Z. Metallkd., 91, No. 7, 594-600 (2000).
14. S. Sato and O. J. Kleppa, "Thermochemistry of liquid alloys of transition metals. I. The systems Mn-Cu and Mn-Sn," Metall. Trans. B, 10, 63-66 (1979).
15. M. A. Turchanin, A. V. Kokhan, and S. V. Porokhnya, "Calorimetric study of the thermodynamic properties of copper-manganese alloys," Rasplavy, No. 3, 17-19 (1994).
16. P. J. Spencer and J. N. Pratt, "Thermodynamic study of liquid manganese-copper alloys," Trans. Faraday Soc., 64, No. 6, 1470-1476 (1968).
17. K. Okajima and H. Sakao, "Activity measurements of the binary Mn-base molten alloys by the TIE method," Trans. Jpn. Inst. Met., 16, No. 2, 87-93 (1975).
18. J. Vrest'al, J. Stepankova, and P. Broz, "Thermodynamics of the copper-manganese system. Knudsen-cell mass spectrometric study of the liquid Cu-Mn system and calculation of the phase diagram," Scand. J. Metall., 25, No. 5, 224-231 (1996).
19. W. Oelsen, E. Schurmann, and C. Florin, "Zur Kalorimetrie und Thermodynamik der Eisen-Kupfer-Legierungen," Arch. Eisenhuttenw, 32, No. 10, 719-728 (1961).
20. Y. Tozaki, Y. Iguchi, Ban-ya-Shiro, and T. Fuwa, "Heat of mixing of iron alloys," in: Int. Symp. Met. Chemistry, Appl. Ferrous Met. (July 19-21, 1971, Shaffield), Shaffield (1971), pp. 130-132.
21. Y. Iguchi, Y. Tozaki, M. Kakizaki, et al., "Calorimetric study of mixing heats of nickel and cobalt alloys," J. Iron Steel Inst. Jap., 67, 925-932 (1981).
22. M. A. Turchanin and S. V. Porokhnya, "Thermodynamics of formation of liquid copper-iron alloys," Raspalvy, No. 1, 9-13 (1995).
23. L. Timberg, J. M. Toguri, and T. Azakami, "A thermodynamic study of copper-iron and copper-cobalt liquid alloys by mass spectrometry," Metall. Trans. B, 12, 275-279 (1981).
24. J. P. Morris and G. R. Zellars, "Vapor pressure of liquid copper and activities in liquid Fe-Cu alloys," J. Met., Trans. AIME, 8, 1086-1091 (1956).
25. U. V. Choudary, J. A. Serkin, and G. R. Belton, "Mass-spectrometric study of the thermodynamics of the iron-copper and iron-copper-carbon(sat) systems at 1600°C," Metall. Trans. B, 6, 399-403 (1975).
26. N. Maruyama and Ban-Ya Shiro, "Measurement of activities in iron-copper, iron-chromium and iron-tin alloys by a transportation method," J. Japan Inst. Metals., 44, No. 12, 1422-1431 (1980).
27. I. V. Nikolaenko and M. A. Turchanin, "Heat of formation of liquid Co-Cu alloys and calculation of the mixing enthalpy for the Co-Cu-Sm system," Rasplavy, No. 5, 80-82 (1989).
28. Y. Iguchi, Y. Tozaki, M. Kakizaki, et al., "Calorimetric study of mixing heats of nickel-cobalt alloys," J. Iron Steel Inst. Jap., 63, 953-961 (1977).
29. P. Taskinen, "Activities and thermodynamic properties of molten Co-Cu alloys," Z. Metallkd., 73, No. 7, 445-450 (1982).
30. J. Kubista and J. Vrestal, "Thermodynamics of the liquid Co-Cu system and calculation of phase diagram," J. Phase Equilibria, 21, No. 2, 125-129 (2000).
31. B. Predel and R. Mohs, "Thermodynamische Untersuchung flussiger Nickel-Kupfer Legierungen," Arch. Eisenhuttenw, 42, No. 8, 575-579 (1971).
32. M. A. Turchanin, S. V. Porokhnya, L. V. Belevtsov, and A. V. Kokhan, "Thermodynamic properties of liquid copper-nickel alloys," Rasplavy, No. 4, 8-12 (1994).
33. J. Tomiska and A. Neckel, "Knudsen-cell mass spectrometry for the determination of the thermodynamic properties of liquid copper-nickel alloys," Int. J. Mass Spectrometry and Ion Physics, 47, 223-226 (1983).
34. L. Sh. Tsemekhman, V. P. Mintsis, B. P., Burylev, et al., "Physical and chemical interactions in the Fe-Cu-Ni system," Izv. VUZov, Chern. Metallurgiya, No. 3, 1-4 (1985).
35. V. V. Berezutskii and G. M. Lukashenko, "Thermodynamic properties of liquid nickel-copper alloys," Ukr. Khim. Zh., No. 10, 1029-1032 (1987).
36. M. A. Turchanin and S. V. Porokhnya, "Excess thermodynamic functions of mixing in the copper-zinc system," Rasplavy, No. 5, 3-8 (1996).
37. E. H. Baker, "Vapor pressures and thermodynamic behavior of liquid zinc-copper alloys at 1150° C," Trans. Inst. Mining Metal., 79, No. 3, C1-C5 (1970).
38. A. Schneider and H. Schmid, "Metal vapor pressures. III. The vapor pressures of Zn and Cd over their binary alloys with Cu, Ag and Au," Z. Elektrochem. Angew. Phys. Chem., 48, 627-639 (1942).
39. L. H. Everett, P. W. M. Jacobs, and J. A. Kitchener, "Activity of zinc in liquid copper-zinc alloys," Acta Metall., 5, 281-284 (1957).
40. M. A. Turchanin, I. V. Belokonenko, and P. G. Agraval, "Applying the theory of ideal associated solution to describe the temperature-concentration dependence of the thermodynamic properties of binary melts," Rasplavy, No. 1, 58-69 (2001).
41. A. A. Turchanin, I. A. Tomilin, M. A. Turchanin, et al., "Enthalpy of formation of liquid, amorphous, and crystal phases in the Ni-Zr system," Zh. Fiz. Khim., 73, No. 11, 1911-1918 (1999).
42. M. A. Turchanin, I. V. Belokonenko, P. G. Agraval, and A. A. Turchanin, "Enthalpies of formation of liquid binary Co + (Ti, Zr, and Hf) alloys," in: Progress in Computing of Physicochemical Properties, Warszawa (1999), pp. 361-369.
43. M. A. Turchanin, "Calorimetric research on the heat of formation of liquid alloys of copper with group IIIA and group IVA metals," Powder Metall. Met. Ceram., 36, No. 5-6, 253-263 (1997).
44. A. A. Turchanin, M. A. Turchanin, and P. G. Agraval, "Thermodynamics of undercooled liquid and amorphous binary metallic alloys," Metastable Nanocrystal. Mat., 10, 481-486 (2001).
45. M. A. Turchanin, I. V. Belokonenko, P. G. Agraval, and A. A. Turchanin, "Enthalpies of formation of liquid binary Ni + (Ti, Zr, and Hf) alloys," Schriften des Forschungszetrums Julich Reihe Energetechnik. Energy Technology, 15, Part 1, 93-97 (2000).
46. M. A. Turchanin and I. V. Nikolaenko, "Enthalpies of formation of liquid (copper + manganese) alloys," Metall. Mater. Trans., B, 28, No. 3, 473-478 (1997).
47. M. A. Turchanin, "Heats of formation of liquid alloys of copper with rare earth metals," in: Proc. 2nd Int. Sci. Conf. on Engineering and Functional Materials (October 14-16, 1997, Lviv, Ukraine), Lviv (1997), pp. 67-68.
48. M. A. Turchanin, S. V. Porokhnya, and V. Ya. Shevchenko, "Calorimetric study of the heat of formation of liquid copper-yttrium alloys," Rasplavy, No. 3, 10-14 (1997).
49. M. A. Turchanin and S. V. Porokhnya, "Mixing enthalpy in the copper-hafnium system," Rasplavy, No. 1, 47-50 (1996).
50. M. A. Turchanin, P. G. Agraval, and I. V. Nikolaenko, "Thermodynamics of alloys and phase equilibria in the copper-iron system," J. Phase Equilibria, 24, No. 4, 307-319 (2003).
51. G. Qi, K. Itagaki, and A. Yazawa, "High temperature heat content measurements of Cu-RE (RE = Y, La, Ce, Pr, Nd) binary systems," Mater. Trans., JIM, 30, No. 4, 273-282 (1989).
52. I. V. Nikolaenko, M. A. Turchanin, and G. I. Batalin, "Studying the thermodynamic properties of liquid alloys of copper with lanthanum and cerium," Rasplavy, 2, No. 1, 25-28 (1988).
53. V. V. Berezutskii and G. M. Lukashenko, "Thermodynamic properties of liquid lanthanum-copper alloys," Rasplavy, No. 6, 98-100 (1990).
54. A. Bykov and E. Pastukhov, "A calorimetric study of alloy formation in Au-Cu and Au-In systems," J. Thermal Anal. Calorim., 60, 845-850 (2000).
55. M. A. Turchanin and P. G. Agraval, "Calculation of metastable phase equilibria with participation of a supercooled fluid and assessment of concentration ranges in which (Co, Ni, Cu)-IVA-metal melts amorphize," in: Physics and Chemistry of Condensed Systems and Interfaces [in Ukrainian], Kyiv. Univ., Kiev (2003), pp. 134-141.
56. V. V. Berezutskii and G. M. Lukashenko, "Thermodynamic properties of liquid copper-yttrium alloys," Zh. Fiz. Khim., 61, No. 5, 1422-1424 (1987).
57. R. A. Oriani, "Thermodynamics of liquid Ag-Au and Au-Cu alloys and the question of strain energy in solid solutions," Acta. Metall., 4, No. 1, 15-25 (1956).
58. R. K. Edwards and M. B. Brodsky, "The thermodynamics of the liquid solutions in the triad Cu-Ag-Au. II. The Cu-Au system," J. Am. Chem. Soc., 78, No. 7, 2983-2989 (1956).
59. S. H. Zhou and F. Sommer, "The enthalpy of formation and the heat capacity of liquid and undercooled liquid Al-Cu-La alloys," Ber. Bunsenges. Phys. Chem., 102, No. 9, 1173-1177 (1998).
60. 20 in the glassy, liquid, and crystalline states," Appl. Phys. Lett., 65, No. 4, 397-399 (1994).
61. S. H. Zhou and F. Sommer, "Calorimetric study of liquid and undercooled liquid Al-Ni-Zr alloys," J. Non-Crystalline Solids, 250-252, 572-576 (1999).
62. J. K. Kovneristyi, É. K. Osipov, and E. A. Trofimova, Physical and Chemical Fundamentals for the Creation of Amorphous Metal Alloys [in Russian], Nauka, Moscow (1983).
63. Yu. V. Yefimov G. Warlimont, G. G. Mukhin, et al., Metastable and Nonequilibrium Alloys [in Russian], Metallurgiya, Moscow (1988).
64. K. Suzuki, H. Fujimori, and K. Hashimoto, Amorphous Metals [in Japanese], Tokyo, (1982).