A neutron diffraction study of alkali cation migration in montmorillonites

Physics and Chemistry of Minerals

Volumn 35, Issue 1, 2008, Pages 49-58

  Gournis, D ^a   Lappas, A ^b   Karakassides, M A ^a   Tobbens D ^c   Moukarika, A ^a  

^a UNIVERSITY OF IOANNINA   (Greece)

^b INSTITUTE OF ELECTRONIC STRUCTURE AND LASER   (Greece)

^c HAHN MEITNER INSTITUT   (Germany)

Author keywords

Hoffman Klemen effect; Infrared reflectance; Lithium migration; Montmorillonite; Neutron diffraction

Indexed keywords

CESIUM; CRYSTAL STRUCTURE; HEAT TREATMENT; LITHIUM; NEUTRON DIFFRACTION; RIETVELD ANALYSIS;

ALKALI CATION MIGRATION; HOFFMAN KLEMEN EFFECT; INFRARED REFLECTANCE; LITHIUM MIGRATION;

CLAY MINERALS;

CATION; CESIUM; CRYSTAL STRUCTURE; CRYSTALLIZATION; HEATING; LITHIUM; MEASUREMENT METHOD; MONTMORILLONITE; NEUTRON DIFFRACTION; RIETVELD ANALYSIS; SATURATION;

EID: 37749003474     PISSN: 03421791     EISSN: 14322021     Source Type: Journal    
DOI: 10.1007/s00269-007-0197-z     Document Type: Article

References (37)

1. Alvero R, Alba MD, Castro MA, Trillo JM (1994) Reversible migration of lithium in montmorillonite. J Phys Chem 98:7848-7853
2. Bacon GE (1975) Neutron diffraction, 3rd edn. Oxford University Press, London
3. Baker DE, Senft JP (1995) Copper. In: Alloway BJ (ed) Heavy metal in soils. Blackie Academic & Professional, London, pp 179-205
4. Calvet R, Prost R (1971) Cation migration into empty octahedral sites and surface properties of clays. Clays Clay Miner 19:175-186
5. Ebina T, Iwasaki T, Chatterjee A (1999) XPS and DFT study on the migration of lithium in montmorillonite. Clay Sci 10:569-581
6. Gates WP, Komadel P, Madejová J, Bujdák J, Stucki JW, Kirkpatrick RJ (2000) Electronic properties of reduced-charge montmorillonites. Appl Clay Sci 16:257-271
7. Gournis D (1998) Effects of γ-irradiation on clays and clay-organic complexes. Ph.D. Thesis, National Technical University of Athens, Athens, Greece, p 57
8. Heller-Kallai L, Mosser C (1995) Migration of Cu ions in Cu montmorillonites heated with and without alkali halides. Clays Clay Miner 43:738-743
9. Hoffmann V, Klemen R (1950) Verlust den Austauschfahiqkeit von Lithiumionen aan Bentonit durch Erhitzung. Z Anorg Allg Chem 262:95-99
10. Hrobáriková J, Madejová J, Komadel P (2001) Effect of heating temperature on Li-fixation, layer charge and properties of fine fractions of bentonites. J Mater Chem 11:1452-1457
11. Jaynes WF, Bigham JM (1987) Charge reduction, octahedral charge and lithium retention in heated Li-saturated smectites. Clays Clay Miner 35:440-448
12. Karakassides MA, Petridis D, Gournis D (1997) Infrared reflectance study of thermally treated Li- and Cs-montmorillonites. Clays Clay Miner 45:649-658
13. Karakassides MA, Gournis D, Petridis D (1999a) An infrared reflectance study of Si-O vibrations in thermally treated alkali-saturated montmorillonites. Clay Miner 34:429-438
14. Karakassides MA, Madejová J, Arvaiová B, Bourlinos A, Petridis D, Komadel P (1999b) Location of Li(I), Cu(II) and Cd(II) in heated montmorillonite: Evidence from specular reflectance infrared and electron spin resonance spectroscopies. J Mater Chem 9:1553-1558
15. Karakassides MA, Gournis D, Simopoulos T, Petridis D (2000) Mössbauer and infrared study of heat-treated nontronite. Clays Clay Miner 48:68-74
16. Komadel P, Bujdák J, Madejová J, Sucha V, Elsass F (1996) Effect of non-swelling layers on the dissolution of reduced-charge montmorillonite in hydrochloric acid. Clay Miner 31:333-345
17. Komadel P, Madejová J, Bujdák J (2005) Preparation and properties of reduced-charge smectites: A review. Clays Clay Miner 53:313-334
18. Konta J (1995) Clay and man: Clay raw materials in the service of man. Appl Clay Sci 10:275-335
19. Luca V, Cardile CM (1988) Thermally induced cation migration in Na and Li montmorillonites. Phys Chem Miner 16:98-103
20. MacEwan DMC (1951) The montmorrillonite minerals: X-ray identification and structure of the clay minerals, Mineralogical Society of Great Britain Monograph, p 86
21. + montmorillonites. Spectrochim Acta A 55:2467-2476
22. Madejová J, Bujdák J, Petit S, Komadel P (2000) Effects of chemical composition and temperature of heating on the infrared spectra of Li-saturated dioctahedral smectites. (I) Mid-infrared region. Clay Miner 35:739-751
23. 2+ in heated montmorillonite: Evidence from far-, mid-, and near-IR regions. Vib Spectrosc 40:80-88
24. Madsen F (1998) Clay mineralogical investigations related to nuclear waste disposal. Clay Miner 33:109-129
25. Méring J (1946) The hydration of montmorillonite. Trans Faraday Soc 42B:205-219
26. Pinnavaia TJ (1983) Interacalated clay catalysts. Science 220:365-371
27. 2+ ion intercalated in montmorillonite: A neutron diffraction with isotopic substitution study. Phys Chem Chem Phys 3:5567-5574
28. Powell DH, Fischer HE, Skipper NT (1998a) The structure of interlayer water in Li-montmorillonite studied by neutron diffraction with isotopic substitution. J Phys Chem B 102:10899-10905
29. Powell DH, Tongkhao K, Kennedy SJ, Slade PG (1998b) Interlayer water structure in Na- and Li-montmorillonite clays. Physica B 241-243:387-389
30. Rietveld HM (1969) A profile refinement method for nuclear and magnetic structures. J Appl Crystallogr 2:65-71
31. Rodriguez- Carvajal J (1993) Recent advances in magnetic structure determination by neutron powder diffraction. Physica B 192:55-69
32. Sposito G, Prost R, Gaultier JP (1983) Infrared spectroscopic study of absorbed water in reduced charged Na/Li-montmorillonites. Clays Clay Miner 31:9-16
33. Srasra E, Bergaya F, Fripiat JJ (1994) Infrared-spectroscopy study of tetrahedral and octahedral substitutions in an interstratified illite-smectite clay. Clays Clay Miner 42:237-241
34. Stackhouse S, Coveney PV (2002) Study of thermally treated lithium montmorillonite by Ab initio methods. J Phys Chem B 106:12470-12477
35. Tettenhorst R (1962) Cation migration in montmorillonites. Am Miner 47:769-773
36. Theng BKG (1974) The chemistry of clay-organic reactions. Wiley, Bristol
37. Theng BKG, Hayashi S, Soma M, Seyama H (1997) Nuclear magnetic resonance and X-ray photoelectron spectroscopic investigation of lithium migration in montmorillonite. Clays Clay Miner 45:718-723