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Volumn 7, Issue 12, 2007, Pages 2768-2773

Anion chain structure controlled behavior of phase transition in quasi-two-dimensional organic metal (EDT-TTF) 4[Hg 3i 8] 1-x

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EID: 37649011623     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg070339y     Document Type: Article
Times cited : (7)

References (21)
  • 3
    • 10344258581 scopus 로고    scopus 로고
    • Mori, T. Chem. Rev. 2004, 104, 4947.
    • (2004) Chem. Rev , vol.104 , pp. 4947
    • Mori, T.1
  • 17
    • 37649006976 scopus 로고    scopus 로고
    • SMART and SAINTPLUS, Area Detector Control and Integration Software, Version 6.01; Bruker Analytical X-Ray Systems: Madison, Wisconsin, 1999
    • SMART and SAINTPLUS, Area Detector Control and Integration Software, Version 6.01; Bruker Analytical X-Ray Systems: Madison, Wisconsin, 1999.
  • 18
    • 37649025069 scopus 로고    scopus 로고
    • SHELXTL, An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Version 5.10; Bruker Analytical X-Ray Systems: Madison, Wisconsin, 1997
    • SHELXTL, An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Version 5.10; Bruker Analytical X-Ray Systems: Madison, Wisconsin, 1997.
  • 20
    • 84868390768 scopus 로고    scopus 로고
    • 2 molecule that is contradictory to the X-ray data.
    • 2-).
  • 21
    • 37649017236 scopus 로고    scopus 로고
    • If both minor and major subchains start from and finish by HgI2 molecules, an empty space of a total equal to one-half of that of [Hg3I8]2- unit fits per each minor subchain (see Figure 7, If a number of minor subchains with one terminal HgI2 molecule is n, a number of minor subchains with two terminal HgI2 is 1/3n and a total number of minor subchains should be 4/3n. There are n vacant of [Hg3I8]2- per n subchains with one terminal HgI2 molecule and l/6n vacant of [Hg 3I8]2- per l/3n subchains with two terminal HgI2 molecules in crystal 1. A total number of vacant [Hg 3I8]2- in crystal 1 derived from the X-ray analysis is 0.027 see Table 2, 0.027, n, l/6n; n, 0.023
    • 2 molecules, is 4/3(0.023) = 0.031. The averaged length of "major" and "minor" subchains in 1 is 6.3/3.1 = 2.0(2) for "minor" and 91/3.1 = 30(4) for "major" ones, that is, 7/8 from the value calculated in the former model.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.