Supramolecular stabilization of hemiacetals of N-alkyl(benz)imidazole aldehydes

Crystal Growth and Design

Volumn 7, Issue 12, 2007, Pages 2380-2381

  Solchinger, Alexander ^a   Wurst, Klaus ^a   Kopacka, Holger ^a   Bildstein, Benno ^a  

^a UNIVERSITY OF INNSBRUCK   (Austria)

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Indexed keywords

EID: 37549039382     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg070377h     Document Type: Article

References (15)

1. Hurd, C. D. J. Chem. Educ. 1966, 43, 527.
2. Hashimoto, M.; Isono, T.; Mano, K. Ber. Bunsenges. Phys. Chem. 1994, 98, 793.
3. Salaun, J. Chem. Rev. 1983, 83, 619.
4. Steinberg, G. M.; Poziomek, E. J.; Hackley, B. E., Jr J. Org. Chem. 1961, 26, 368.
5. Erickson, J. L. E.; Campbell, C. R., Jr J. Am. Chem. Soc. 1954, 76, 4472.
6. Solchinger, A. Ph.D. Dissertation, University of Innsbruck, Innsbruck, Austria, 2006.
7. A patent claim, although without any experimental proof, has been published: Hayashi, M.; Tanouchi, T.; Takatsuki; Kawamura, M. I.; Kajiwara, I.; Iguchi, Y.; Takatsuki. German Patent 2917456, 1979.
8. 2O, (e) amberlyst/acetone.
9. 2.
10. Reaction conditions: 4 equiv of DIBAL in hexane solution, 3 h stirring at -70 °C, hydrolysis by dropwise addition of dry methanol at -70 °C.
11. -1.
12. -1.
13. int = 0.0355], final R indices (133 parameters) for 1187 independent reflections [I< 2σ(I)] are R1 = 0.0393, wR2 = 0.0917, GOF = 1.054.
14. Chen, C.-L.; Su, C.-Y.; Cai, Y.-P.; Zhang, H.-X.; Xu, A.-W.; Kang, B.-S.; zur Loye, H.-C. Inorg. Chem. 2003, 42, 3738.
15. int = 0.0368], final R indices (132 parameters) for 1397 independent reflections [I < 2σ(I)] are R1 = 0.0509, wR2 = 0.1293, GOF = 1.061.