High temperature calorimetric studies of heat of solution of NiO, CuO, La2O3, TiO2, HfO2 in sodium silicate liquids

Geochimica et Cosmochimica Acta

Volumn 72, Issue 2, 2008, Pages 590-601

  Linard, Yannick ^a   Wilding, Martin C ^a   Navrotsky, Alexandra ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CALORIMETRY; CATION; CONCENTRATION (COMPOSITION); ENTHALPY; HIGH TEMPERATURE; SILICATE; SODIUM; TEMPERATURE EFFECT;

EID: 37449021431     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2007.10.004     Document Type: Article

References (39)

1. Barin I. Thermochemical Data of Pure Substances (1989), VCH Verlagsgesellschaft, Weinheim
2. Bottinga Y., and Richet P. Thermodynamics of liquid silicates, a preliminary report. Earth Planet. Sci. Lett. 40 (1978) 382-400
3. Dickinson J.E., and Hess P.C. Rutile solubility and titanium coordination in silciate melts. Geochim. Cosmochim. Acta 44 (1985) 2289-2296
4. Ellison A.J., and Hess P.C. Solution behavior of +4 cations in high silica melts: petrologic and geochemical implications. Contrib. Mineral. Petrol. 94 3 (1986) 343-351
5. Ellison A. J. G. and Navrotsky A. (1990) Thermochemistry and structure of model waste glass compositions. In Scientific Basis for Nuclear Waste Management XIII (ed. V. M. Oversby and P. W. Brown), pp. 193-207.
6. 4 and Ni-bearing Na-disilicate glass and melt. Chem. Geol. 128 1 (1996) 93-106
7. Farges F., Brown Jr. G.E., Navrotsky A., Gan H., and Rehr J.J. Coordination chemistry of Ti(IV) in silicate glasses and melts. II. Glasses at ambient temperature and pressure. Geochim. Cosmochim. Acta 60 16 (1996) 3039-3053
8. Farges F., Brown Jr. G.E., Navrotsky A., Gan H., and Rehr J.J. Coordination chemistry of Ti(IV) in silicate glasses and melts. III. Glasses and melts from ambient to high temperatures. Geochim. Cosmochim. Acta 60 16 (1996) 3055-3065
9. Farges F., Brown Jr. G.E., and Rehr J.J. Coordination chemistry of Ti(IV) in silicate glasses and melts. I. XAFS study of Ti coordination in oxide model compounds. Geochim. Cosmochim. Acta 60 16 (1996) 3023-3038
10. Galoisy L., and Calas G. Structural environment of nickel in silicate glass/melt systems. Part 1. Spectroscopic determination of coordination states. Geochim. Cosmochim. Acta 57 15 (1993) 3613-3626
11. Galoisy L., and Calas G. Structural environment of nickel in silicate glass/melt systems: Part 2. Geochemical implications. Geochim. Cosmochim. Acta 57 15 (1993) 3627-3633
12. Gan H. (1994) The speciation of solution properties of high field strength cations: P5+, Ti4+ and B2+ in aluminosilicate melt., Ph D Thesis, Brown University, Providence, RI.
13. 4+ in silicate melts: energetics from high-temperature calorimetric studies and implications for melt structure. Geochim. Cosmochim. Acta 60 21 (1996) 4123-4131
14. Grundy N.A., Hallstedt B., and Gauckler L.J. Thermodynamic assessment of the Lanthanum-Oxygen system. J. Phase Equilib. 22 2 (2001) 105-113
15. 3, with comments on selected oxygen buffer reactions. Am. Mineral. 75 7-8 (1990) 781-790
16. Hess P.C. Polymer model of silicate melts. Geochim. Cosmochim. Acta 35 3 (1971) 289-306
17. Hess P.C. Polymerization model of silicate melts. In: Hargraves R.B. (Ed). Physics of Magmatic Processes vol. 3-49 (1980), Princeton University Press, Princeton, NJ
18. Hess P. C. (1995) Thermodynamic mixing properties and the structure of silicate melts. In Reviews In Mineralogy. Vol. 32-Structure dynamics and properties of silicate melts (eds. J. F. Stebbins, P. F. McMillan and D. B. Dingwell). Mineralogical Society of America, USA.
19. JANAF (1985) Thermochemical tables (third ed.). J. Phys. Chem. Ref. Data, Suppl. 1(14), 1-1856.
20. Keppler H. Crystal field spectra and geochemistry of transition metal ions in silicate melts and glasses. Am. Mineral. 77 1-2 (1992) 62-75
21. Keppler H., and Bagdassarov N. The speciation of Ni and Co in silicate melts from optical absorption spectra to 1500 °C. Chem. Geol. 158 1 (1999) 105-115
22. Lange R., Cashman K.V., and Navrotsky A. Direct measurements of latent heat during crystallization and melting of a ugandite and an olivine basalt. Contrib. Mineral. Petrol. 118 (1994) 169-181
23. 3-bearing silicate liquids. Contrib. Mineral. Petrol. 110 2-3 (1992) 311-320
24. Lee S.K., and Stebbins J.F. The degree of aluminum avoidance in aluminosilicate glasses. Am. Mineral. 84 5-6 (1999) 937-945
25. 2+ in potassium borate glass and melt to 1000 °C. Commun. Am. Ceram. Soc. 67 (1984) 33-34
26. 4 spinel: thermally induced spin unpairing transition. Physics and Chemistry of Minerals 19 2 (1992) 88-95
27. Moynihan C. T. (1995) Structural relaxation and the glass transition. In Reviews In Mineralogy. Vol. 32-Structure, Dynamics and Properties of Silicate Melts (eds. J. F. Stebbins, P. F. McMillan and D. B. Dingwell). Mineralogical Society of America, USA.
28. Müller F. Thermochemical investigation of binary liquid mixtures in glass-forming oxide systems. J. Phase Equilib. 15 3 (1994) 285-294
29. Navrotsky A. (1995) Energetics of silicate melts. In Reviews In Mineralogy. Vol. 32-Structure, Dynamics and Properties of Silicate Melts (eds. J. F. Stebbins, P. F. McMillan and D. B. Dingwell). Mineralogical Society of America, USA.
30. Navrotsky A., and Kleppa O.J. Calorimetric study of molten sodium molybdate-molybdenum trioxide mixtures at 970 K. Inorg. Chem. 6 11 (1967) 2119-2121
31. Nowak M., and Keppler H. The influence of water on the environment of transition metals in silicate glasses. Am. Mineral. 83 (1998) 43-50
32. Oestvold T., and Kleppa O.J. Thermochemistry of liquid borates. II. Partial enthalpies of solution of boric oxide in its liquid mixtures with lithium, sodium, and potassium oxides. Inorg. Chem. 9 6 (1970) 1395-1400
33. Richet P. and Bottinga Y. (1995) Rheology and configurational entropy of silicate melts. In Reviews In Mineralogy. Vol. 32-Structure, Dynamics and Properties of Silicate Melts (eds. J. F. Stebbins, P. F. McMillan and D. B. Dingwell). Mineralogical Society of America, USA.
34. 5 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull. 2131 (1995) 456
35. 5 Pascals) pressure and at higher temperatures. U.S. Geol. Survey Bull. (1978) 1452
36. 2 (M = Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Pb). J. Am. Ceram. Soc. 67 (1984) 606-610
37. 6; A = K, Rb, Cs; B = Be, Mg, Fe, Co, Ni, Cu, Zn, Cd; C = B, AI, Ga, Fe, Cr; X = Si, Ge). Z. Anorg. Allg. Chem. 576 (1989) 223-230
38. Wilding M.C., and Navrotsky A. The dissolution of silica and alumina in silicate melts: in situ high temperature calorimetric studies. N. Jb. Miner. Abh. 172 (1998) 177-201
39. 3 in silicate liquids. J. Non-Cryst. Solids 265 3 (2000) 238-251