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Volumn 17, Issue 2, 1998, Pages 125-127

Oxidative addition of dimesitylphosphine to platinum(0): P-H vs P-C activation

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EID: 3743120482     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970754v     Document Type: Article
Times cited : (32)

References (31)
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    • For related observations, see: (a) C-H vs C-Si addition Hofmann, P.; Heiss, H.; Neiteler, P.; Muller, G.; Lachmann, J. Angew. Chem., Int. Ed. Engl. 1990, 29, 880-882. Hofmann, P. In Organosilicon Chemistry: From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1994; pp 231-250. (b) N-H vs N-C addition Bonanno, J. B.; Henry, T. P.; Neithamer, D. R.; Wolczanski, P. T.; Lobkovsky, E. B. J. Am. Chem. Soc. 1996, 118, 5132-5133. (c) C-H vs C-C addition Rybtchinski, B.; Vigalok, A.; Ben-David, Y.; Milstein, D. J. Am. Chem. Soc. 1996, 118, 12406-12415.
    • (1990) Angew. Chem., Int. Ed. Engl. , vol.29 , pp. 880-882
    • Hofmann, P.1    Heiss, H.2    Neiteler, P.3    Muller, G.4    Lachmann, J.5
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    • Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany
    • For related observations, see: (a) C-H vs C-Si addition Hofmann, P.; Heiss, H.; Neiteler, P.; Muller, G.; Lachmann, J. Angew. Chem., Int. Ed. Engl. 1990, 29, 880-882. Hofmann, P. In Organosilicon Chemistry: From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1994; pp 231-250. (b) N-H vs N-C addition Bonanno, J. B.; Henry, T. P.; Neithamer, D. R.; Wolczanski, P. T.; Lobkovsky, E. B. J. Am. Chem. Soc. 1996, 118, 5132-5133. (c) C-H vs C-C addition Rybtchinski, B.; Vigalok, A.; Ben-David, Y.; Milstein, D. J. Am. Chem. Soc. 1996, 118, 12406-12415.
    • (1994) Organosilicon Chemistry: From Molecules to Materials , pp. 231-250
    • Hofmann, P.1
  • 7
    • 0030152367 scopus 로고    scopus 로고
    • For related observations, see: (a) C-H vs C-Si addition Hofmann, P.; Heiss, H.; Neiteler, P.; Muller, G.; Lachmann, J. Angew. Chem., Int. Ed. Engl. 1990, 29, 880-882. Hofmann, P. In Organosilicon Chemistry: From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1994; pp 231-250. (b) N-H vs N-C addition Bonanno, J. B.; Henry, T. P.; Neithamer, D. R.; Wolczanski, P. T.; Lobkovsky, E. B. J. Am. Chem. Soc. 1996, 118, 5132-5133. (c) C-H vs C-C addition Rybtchinski, B.; Vigalok, A.; Ben-David, Y.; Milstein, D. J. Am. Chem. Soc. 1996, 118, 12406-12415.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 5132-5133
    • Bonanno, J.B.1    Henry, T.P.2    Neithamer, D.R.3    Wolczanski, P.T.4    Lobkovsky, E.B.5
  • 8
    • 0030443080 scopus 로고    scopus 로고
    • For related observations, see: (a) C-H vs C-Si addition Hofmann, P.; Heiss, H.; Neiteler, P.; Muller, G.; Lachmann, J. Angew. Chem., Int. Ed. Engl. 1990, 29, 880-882. Hofmann, P. In Organosilicon Chemistry: From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1994; pp 231-250. (b) N-H vs N-C addition Bonanno, J. B.; Henry, T. P.; Neithamer, D. R.; Wolczanski, P. T.; Lobkovsky, E. B. J. Am. Chem. Soc. 1996, 118, 5132-5133. (c) C-H vs C-C addition Rybtchinski, B.; Vigalok, A.; Ben-David, Y.; Milstein, D. J. Am. Chem. Soc. 1996, 118, 12406-12415.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 12406-12415
    • Rybtchinski, B.1    Vigalok, A.2    Ben-David, Y.3    Milstein, D.4
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    • note
    • 2 per 1 equiv of 1 are complete in ∼250 h, with similar yields.
  • 12
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    • note
    • For experimental details and characterization data, see the Supporting Information.
  • 14
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    • note
    • 3Pt: C, 61.18; H, 5.48. Found: C, 60.95; H, 5.34.
  • 15
    • 3743117153 scopus 로고    scopus 로고
    • note
    • 11)(PHMes) were observed.
  • 19
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    • note
    • 4) and competitive C-H and C-Si oxidative addition and disproportionation steps.
  • 20
    • 0011786410 scopus 로고
    • For examples of reversible P-H activation, see: (a) Baker, K. T.; Calabrese, J. C.; Glassman, T. E. Organometallics 1988, 7, 1889-1891. (b) Baker, R. T.; Calabrese, J. C.; Harlow, R. L.; Williams, I. D. Organometallics 1993, 12, 830-841. See also: Schunn, R. A. Inorg. Chem. 1973, 12, 1573-1579.
    • (1988) Organometallics , vol.7 , pp. 1889-1891
    • Baker, K.T.1    Calabrese, J.C.2    Glassman, T.E.3
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    • 0000030781 scopus 로고
    • For examples of reversible P-H activation, see: (a) Baker, K. T.; Calabrese, J. C.; Glassman, T. E. Organometallics 1988, 7, 1889-1891. (b) Baker, R. T.; Calabrese, J. C.; Harlow, R. L.; Williams, I. D. Organometallics 1993, 12, 830-841. See also: Schunn, R. A. Inorg. Chem. 1973, 12, 1573-1579.
    • (1993) Organometallics , vol.12 , pp. 830-841
    • Baker, R.T.1    Calabrese, J.C.2    Harlow, R.L.3    Williams, I.D.4
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    • For examples of reversible P-H activation, see: (a) Baker, K. T.; Calabrese, J. C.; Glassman, T. E. Organometallics 1988, 7, 1889-1891. (b) Baker, R. T.; Calabrese, J. C.; Harlow, R. L.; Williams, I. D. Organometallics 1993, 12, 830-841. See also: Schunn, R. A. Inorg. Chem. 1973, 12, 1573-1579.
    • (1973) Inorg. Chem. , vol.12 , pp. 1573-1579
    • Schunn, R.A.1
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    • As pointed out by a referee, the definition of the bond strengths incorporates any changes in the properties of the ancillary ligand bonds during this transformation. For further discussion of this point, see: Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1991, 10, 1875-1887. For similar thermodynamic analyses of proton transfers in the Pt(dppe)(Me)(X) system, see: (a) Bryndza, H. E.; Fong, L. K.; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456. (b) Bryndza, H. E.; Domaille, P. J.; Tam, W.; Fong, L. K.; Paciello, R. A.; Bercaw, J. E. Polyhedron 1988, 7, 1441-1452.
    • (1991) J. Am. Chem. Soc. , vol.10 , pp. 1875-1887
    • Hartwig, J.F.1    Andersen, R.A.2    Bergman, R.G.3
  • 25
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    • As pointed out by a referee, the definition of the bond strengths incorporates any changes in the properties of the ancillary ligand bonds during this transformation. For further discussion of this point, see: Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1991, 10, 1875-1887. For similar thermodynamic analyses of proton transfers in the Pt(dppe)(Me)(X) system, see: (a) Bryndza, H. E.; Fong, L. K.; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456. (b) Bryndza, H. E.; Domaille, P. J.; Tam, W.; Fong, L. K.; Paciello, R. A.; Bercaw, J. E. Polyhedron 1988, 7, 1441-1452.
    • (1987) J. Am. Chem. Soc. , vol.109 , pp. 1444-1456
    • Bryndza, H.E.1    Fong, L.K.2    Paciello, R.A.3    Tam, W.4    Bercaw, J.E.5
  • 26
    • 0001559867 scopus 로고
    • As pointed out by a referee, the definition of the bond strengths incorporates any changes in the properties of the ancillary ligand bonds during this transformation. For further discussion of this point, see: Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1991, 10, 1875-1887. For similar thermodynamic analyses of proton transfers in the Pt(dppe)(Me)(X) system, see: (a) Bryndza, H. E.; Fong, L. K.; Paciello, R. A.; Tam, W.; Bercaw, J. E. J. Am. Chem. Soc. 1987, 109, 1444-1456. (b) Bryndza, H. E.; Domaille, P. J.; Tam, W.; Fong, L. K.; Paciello, R. A.; Bercaw, J. E. Polyhedron 1988, 7, 1441-1452.
    • (1988) Polyhedron , vol.7 , pp. 1441-1452
    • Bryndza, H.E.1    Domaille, P.J.2    Tam, W.3    Fong, L.K.4    Paciello, R.A.5    Bercaw, J.E.6
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    • Martinho Simoes, J. A.; Beauchamp, J. L. Chem. Rev. 1990, 90, 629-688. Because dppe has a greater trans influence than Cl, the Pt-H bond strength in 2 is likely to be lower than this estimated value.
    • (1990) Chem. Rev. , vol.90 , pp. 629-688
    • Martinho Simoes, J.A.1    Beauchamp, J.L.2
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    • F. R. Hartley, Ed.; John Wiley and Sons: New York
    • Pilcher, G. In The Chemistry of Organophosphorus Compounds; F. R. Hartley, Ed.; John Wiley and Sons: New York, 1990; Vol. 1, pp 127-136.
    • (1990) The Chemistry of Organophosphorus Compounds , vol.1 , pp. 127-136
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    • note
    • 2 and the model compounds; this reflects the limited data available in organophosphorus thermochemistry (see ref 18). Because of the relatively crude nature of these approximations, the main value of this analysis is its prediction about relative Pt-P bond strengths.


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