Novel radical ring-opening polymerization of vinyloxirane derivatives: Synthesis and polymerization of 2-vinyl-1-oxaspiro[2.5]octanes

Macromolecules

Volumn 31, Issue 25, 1998, Pages 9096-9098

  Koizumi, Toshio ^a   Ando, Takanori ^a   Kojima, Takakazu ^a   Endo, Takeshi ^b  

^a NATIONAL DEFENSE ACADEMY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CROSSLINKING; FREE RADICAL POLYMERIZATION; GEL PERMEATION CHROMATOGRAPHY; MOLECULAR STRUCTURE; NITROGEN COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; PEROXIDES; REACTION KINETICS; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL);

AZOBISISOBUTYRONITRILE; BENZOYL PEROXIDE; POLYDISPERSITY; POLYVINYLOXIRANE;

VINYL RESINS;

EID: 3743117376     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9807668     Document Type: Article

References (10)

1. (a) Endo, T.; Yokozawa, T. In New Methods for Polymer Synthesis; Mijs, W. J., Ed.; Plenum Press: New York, 1992; p 155.
2. (b) Bailey, W. J.; Chen, P. Y.; Chen, S.-C.; Chiao, W.-B.; Endo, T.; Gapud, B.; Kuruganti, V.; Lin, Y.-N.; Ni, Z.; Pan, C.-Y.; Shaffer, S. E.; Sidney, L.; Wu, S.-R.; Yamamoto, N.; Yamazaki, N.; Yonezawa, K.; Zhou, L.-L. Makromol. Chem., Macromol. Symp. 1986, 6, 81.
3. (a) Cho, I.; Kim, J.-B. J. Polym. Sci. Polym. Lett. Ed. 1983, 21, 433.
4. (b) Endo, T.; Kanda, N. J. Polym. Sci. Polym. Chem. Ed. 1985, 23, 1931.
5. (c) Endo, T.; Suga, K.; Orikasa, Y.; Kojima, S. J. Appl. Polym. Sci. 1989, 37, 1815.
6. (d) T. Koizumi, Y. Nojima, and T. Endo, J. Polym. Sci. Polym. Chem. Ed. 1993, 31, 3489.
7. Murata, K. J. Polym. Sci. Polym. Chem. Ed. 1972, 10, 3673.
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10. A typical procedure: 3a or 3b (2 mmol), initiator, and chlorobenzene were placed in an ampule tube. The tube was degassed and sealed under reduced pressure. The polymerization was carried out for 24 or 48 h. The reaction mixture was poured into a plenty of n-hexane to precipitate polymer. The resulting polymer was filtered, washed with n-hexane, and dried in vacuo. (The detailed reaction conditions are shown in Table 1.)