Synthesis, structure and characterization of [Mg7(μ3-OCH2CH2OMe)6(μ-OCH2CH2OMe)6][Al(n-Bu)4]2 - A cationic heptanuclear magnesium complex consisting of discrete cations and tetrabutylaluminate anions

Polyhedron

Volumn 27, Issue 1, 2008, Pages 151-156

  Linnert, Matthias ^a   Bruhn, Clemens ^b   Schmidt, Harry ^a   Herzog, Renate ^a   Steinborn, Dirk ^a  

^a MARTIN LUTHER UNIVERSITY HALLE WITTENBERG   (Germany)

^b Abt Metallorganische Chemie   (Germany)

Author keywords

27Al NMR spectroscopy; Alkyl aluminates; Crystal structures; Magnesium complexes; Oligonuclear complexes

Indexed keywords

ALUMINUM COMPOUNDS; CRYSTAL STRUCTURE; MAGNESIUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); X RAY POWDER DIFFRACTION;

27AL NMR SPECTROSCOPY; ALKYL ALUMINATE; CATIONICS; CRYSTALS STRUCTURES; DIBUTYL-MAGNESIUM; MAGNESIUM COMPLEXES; N-BUTYLLITHIUM; NMR-SPECTROSCOPY; OLIGONUCLEAR COMPLEXES; PRODUCT YIELDS;

NEGATIVE IONS;

EID: 37349089801     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2007.08.039     Document Type: Article

References (28)

1. Bradley D.C. Chem. Rev. 89 (1989) 1317
2. Herrmann W.A., Huber N.W., and Runte O. Angew. Chem. 107 (1995) 2371
3. Hanusa T.P. In: McCleverty J.A., and Meyer T.J. (Eds). Comprehensive Coordination Chemistry II vol. 3 (2004), Elsevier/Pergamon, Amsterdam 1
4. Resconi L., Chadwick J.C., and Cavallo L. In: Mingos D.M.P., and Crabtree R.H. (Eds). Comprehensive Organometallic Chemistry III vol. 4 (2007), Elsevier, Amsterdam 1006
5. Albaric L., Hovnanian N., Julbe A., Guizard C., Alvarez-Larena A., and Piniella J.F. Polyhedron 16 (1997) 587
6. Sobota P., Utko J., Janas Z., and Szafert S. Chem. Commun. (1996) 1923
7. Sobota P., Utko J., Sztajnowska K., Ejfler J., and Jerzykiewicz L.B. Inorg. Chem. 39 (2000) 235
8. Janas Z., Jerzykiewicz L.B., Sobota P., and Utko J. New J. Chem. (1999) 185
9. Sobota P., Utko J., Ejfler J., and Jerzykiewicz L.B. Organometallics 19 (2000) 4929
10. Cambridge Structural Database (CSD): Cambridge Crystallographic Data Centre, University Chemical Laboratory, Cambridge, UK.
11. Tsirelson V.G., Avilov A.S., Abramov Y.A., Belokoneva E.L., Kitaneh C.R., and Feil D. Acta Crystallogr., Sect. B 54 (1998) 8
12. Gerteis R.L., Dickerson R.E., and Brown T.L. Inorg. Chem. 3 (1964) 872
13. Medley J.H., Fronczek F.R., Ahmad N., Day M.C., Rogers R.D., Kerr C.R., and Atwood J.L. J. Cryst. Spectr. Res. 15 (1985) 99
14. Sizov A.I., Zvukova T.M., Bulychev B.M., and Belsky V.K. J. Organomet. Chem. 603 (2000) 167
15. Wolfrum R., Sauermann G., and Weiss E. J. Organomet. Chem. 18 (1969) 27
16. Schade C., and Ragué Schleyer P.v. Adv. Organomet. Chem. 27 (1987) 169
17. Craig F.J., Kennedy A.R., Mulvey R.E., and Spicer M.D. Chem. Commun. (1996) 1951
18. Komiya S., Yamamoto T., and Yamamoto A. Acta Crystallogr., Sect. B 35 (1979) 2702
19. Nakamura H., Nakayama Y., Yasuda H., Maruo T., Kanehisa N., and Kai Y. Organometallics 19 (2000) 5392
20. Andrikopoulos P.C., Armstrong D.R., Hevia E., Kennedy A.R., Mulvey R.E., and O'Hara C.T. Chem. Commun. (2005) 1131
21. Gizbar H., Vestfrid Y., Chusid O., Gofer Y., Gottlieb H.E., Marks V., and Aurbach D. Organometallics 23 (2004) 3826
22. Yamamoto O. Chem. Lett. (1975) 511
23. Stender M., Segerer U., Sieler J., and Hey-Hawkins E. Z. Anorg. Allg. Chem. 624 (1998) 85 and references cited therein
24. Claridge T.D.W. High-resolution NMR Techniques in Organic Chemistry (1999), Pergamon Press, Amsterdam p. 41
25. Marcus Y., and Hefter G. Chem. Rev. 106 (2006) 4585
26. Schöberl A., and Wagner A. In: Müller E. (Ed). Houben-Weyl, Methoden der Organischen Chemie vol. IX (1955), Thieme-Verlag, Stuttgart 7 and 97
27. Sheldrick G.M. shelxl-97, Programs for Structure Determination (1990), University of Göttingen, Göttingen, Germany
28. Sheldrick G.M. shelxl-97, Programs for Structure Determination (1997), University of Göttingen, Göttingen, Germany