Enhanced O2 solubility by RE2O3 (RE = La, Gd) additions in molten carbonate electrolytes for MCFC

Journal of Molecular Liquids

Volumn 138, Issue 1-3, 2008, Pages 107-112

  Scaccia, Silvera ^a   Frangini, Stefano ^a   Dellepiane, Serena ^b  

^a ENEA   (Italy)

^b ANSALDO ENERGIA   (Italy)

Author keywords

Lanthanum and gadolinium; Lithium Potassium and sodium carbonate; Oxygen dissolution mechanism; Oxygen solubility

Indexed keywords

CARBONATES; DISSOLUTION; DISSOLVED OXYGEN; FUEL CELLS; GADOLINIUM; LANTHANUM; SOLUBILITY;

MELT COMPOSITION; OXYGEN DISSOLUTION MECHANISM; OXYGEN SOLUBILITY; SODIUM CARBONATE;

ELECTROLYTES;

EID: 37249076627     PISSN: 01677322     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molliq.2007.09.006     Document Type: Article

References (36)

1. Williams M.C., and Maru H.C. J. Power Sources 160 (2006) 863
2. Bishoff M. J. Power Sources 154 (2006) 461
3. Brdar D., and Farooque M. The Fuel Cell Review 2 (2005) 15
4. Farooque M., Yuh C., and Maru H.C. MRS Bulletin 30 (2005) 602
5. Baumgartner C.E. J. Electrochem. Soc. 131 (1984) 1850
6. Hong M.Z., Bae S.C., Lee H.S., Lee H.C., Kim Y.M., and Kim K. Electrochim. Acta 48 (2003) 4213
7. Mitsushima S., Matsuzawa K., Kamiya N., and Ota K. Electrochim. Acta 47 (2002) 3823
8. Feng B., and Chen H. J. Electroanal. Chem. 501 (2001) 128
9. Ganesan P., Colon H., Haran B., and Popov B.N. J. Power Sources 115 (2003) 12
10. Bloom I., Lanagan M.T., Krumpelt M., and Smith J.L. J. Electrochem. Soc. 146 (1999) 1336
11. Huang B., Li F., Yu Q.C., Chen G., Zhao B.Y., and Hu K.A. J. Power Sources 128 (2004) 135
12. T.D. Kaun, I.D. Bloom, M. Krumpelt, Non-segregating electrolytes for molten carbonate fuel cells, DOE REPORT 1997.
13. D. Kaun, M. Roche, High performance electrolytes for MCFC, US patent, No 5,942,345, Aug. 24, 1999.
14. P Ang P.G., and Sammells A.F. J. Electrochem. Soc. 127 (1980) 1287
15. Tanimoto K., Miyazaki Y., Yanagida M., Tanase S., Kojima T., Ohtori N., Okuyama H., and Kodama T. J. Power Sources 39 (1992) 285
16. Wendt H., Brenscheidt T.h., and Kah M. High Temp. Mater. Process 2 (1998) 597
17. Mitsushima S., Ota K., Kato S., Asano S., Yashitake H., and Kamiya N. J. Electrochem. Soc. 139 (1992) 667
18. K. Ota, Proceedings of 7th International Symposium on Molten Salts Chemistry & Technology, 29 August/2 September 2005 Toulouse France p. 405.
19. Matsuzawa K., Tatezawa G., Matsuda Y., Mitsushima S., Kamiya N., and Ota K. J. Electrochem. Soc. 152 (2005) A1116
20. Matsuzawa K., Mizusaki T., Mitsushima S., Kamiya N., and Ota K. J. Power Sources 140 (2005) 258
21. Scaccia S. J. Mol. Liq. 116 (2005) 67
22. Escudero M.J., Rodrigo T., and Daza L. Catal. Today 107-108 (2005) 377
23. Huang B., Chen G., Li F., Yu Q., and Hu K. Electrochim. Acta 49 (2004) 5055
24. Frangini S., and Scaccia S. J. Electrochem. Soc. 152 (2005) A2155
25. Mitsushima S., Takahashi N., Kamiya N., and Ota K. Electrochemistry 73 (2005) 651
26. Frangini S., and Scaccia S. J. Electrochem. Soc. 151 (2004) A1251
27. Scaccia S., and Frangini S. Talanta 64 (2004) 791
28. Smith S.W., Vogel W.M., and Kapelner S. J. Electrochem. Soc. 129 (1982) 1668
29. Reeve R.W., and Tseung A.C.C. J. Electroanal. Chem. 403 (1996) 85
30. Scaccia S., and Frangini S. J. Mol. Liq. 129 (2006) 133
31. Iizuka M. J. Electrochem. Soc. 145 (1998) 84
32. Masui T., Koyabu K., Tamura S., and Imanaka N. J. Mater. Sci. 40 (2005) 4121
33. Olafsen A., Larsson A.K., Fjellvag H., and Hauback B.C. J. Solid State Chem. 158 (2001) 14
34. Shirsat A.N., Kaimal K.N.G., Bharadwaj S.R., and Das D. J. Physics and Chem. Solids 66 (2005) 1122
35. Appleby A.J., and Van Drunen C. J. Electrochem. Soc. 127 (1980) 1655
36. Miller J.C., and Miller J.N. Statistics for Analytical Chemistry. 2nd ed. (1988), John Wiley & Sons, New York