Decomposition kinetics of ammonia in gaseous stream by a nanoscale copper-cerium bimetallic catalyst

Journal of Hazardous Materials

Volumn 150, Issue 1, 2008, Pages 53-61

  Hung, Chang Mao ^a  

^a YUNG TA INSTITUTE OF TECHNOLOGY AND COMMERCE   (Taiwan)

Author keywords

Ammonia; Kinetic; Nanoscale copper cerium bimetallic catalyst; Selective catalytic oxidation (SCO); Tubular fixed bed reactor (TFBR)

Indexed keywords

CATALYST ACTIVITY; CHEMICAL REACTORS; OXIDATION; REACTION KINETICS;

NANOSCALE COPPER-CERIUM BIMETALLIC CATALYST; SELECTIVE CATALYTIC OXIDATION (SCO); TUBULAR FIXED-BED REACTOR (TFBR);

AMMONIA;

AMMONIA; CERIUM; COPPER;

AMMONIA; CATALYST ACTIVITY; CHEMICAL REACTORS; OXIDATION; REACTION KINETICS;

CATALYSIS; DECOMPOSITION; EXPERIMENTAL STUDY; OXIDATION; PARTICLE SIZE; PRECIPITATION (CHEMISTRY); REACTION KINETICS; TRANSMISSION ELECTRON MICROSCOPY;

ARTICLE; CATALYST; DECOMPOSITION; EXPERIMENTAL STUDY; KINETICS; OXIDATION; TRANSMISSION ELECTRON MICROSCOPY;

AMMONIA; CATALYSIS; CERIUM; COPPER; MODELS, CHEMICAL; OXIDATION-REDUCTION; RIVERS; WATER POLLUTANTS, CHEMICAL; WATER POLLUTION;

EID: 37249076007     PISSN: 03043894     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jhazmat.2007.04.044     Document Type: Article

References (35)

1. Mojtahedi W., and Abbasian J. Catalytic decomposition of ammonia in a fuel gas at high temperature and pressure. Fuel 74 (1995) 1698-1703
2. x emissions in Canada. Environ. Pollut. 102 (1998) 187-194
3. 3 under strongly oxidizing conditions. Catal. Today 59 (2000) 365-371
4. Lou J.C., Hung C.M., and Yang S.F. Selective catalytic oxidation of ammonia over copper-cerium composite catalyst. J. Air Waste Manage. Assoc. 54 (2004) 68-76
5. Kim N.J., Hirai M., and Shoda M. Comparison of organic and inorganic packing materials in the removal of ammonia gas in biofilters. J. Hazard. Mater. B72 (2000) 77-90
6. Chung Y.C., Huang C., Liu C.H., and Bai H. Biotreatment of hydrogen sulfide- and ammonia-containing waste gases by fluidized bed bioreactor. J. Air Waste Manage. Assoc. 51 (2001) 163-172
7. Huang T.L., Cliffe K.R., and Macinnes J.M. The removal of ammonia from water by a hydrophobic catalyst. Environ. Sci. Technol. 34 (2000) 4804-4809
8. Burch R., and Southward B.W.L. The nature of the active metal surface of catalysts for the clean combustion of biogas containing ammonia. J. Catal. 198 (2001) 286-295
9. Hasegawa T., and Sato M. Study of ammonia removal from coal-gasified fuel. Combust. Flame 114 (1998) 246-258
10. Wójtowicz M.A., Miknis F.P., Grimes R.W., Smith W.W., and Serio M.A. Control of nitric oxide, nitrous oxide, and ammonia emissions using microwave plasmas. J. Hazard. Mater. 74 (2000) 81-89
11. de Vooys A.C.A., Koper M.T.M., van Santen R.A., and van Veen J.A.R. The role of adsorbates in the electrochemical oxidation of ammonia on noble and transition metal electrodes. J. Electroanal. Chem. 506 (2001) 127-137
12. Mangun C.L., Braatz R.D., Economy J., and Hall A.J. Fixed bed adsorption of acetone and ammonia onto oxidized activated carbon fibers. Ind. Eng. Chem. Res. 38 (1999) 3499-3504
13. Muenter A.H., and Koehler B.G. Adsorption of ammonia on soot at low temperatures. J. Phys. Chem. A 104 (2000) 8527-8534
14. Schmidt-Szałowski K., Krawczyk K., and Petryk J. The properties of cobalt oxide catalyst for ammonia oxidation. Appl. Catal. A: General 175 (1998) 147-157
15. Wang W., Padban N., Ye Z., Andersson A., and Bjerle I. Kinetic of ammonia decomposition in hot gas cleaning. Ind. Eng. Chem. Res. 38 (1999) 4175-4182
16. Curtin T., Regan F.O., Deconinck C., Knu{combining double acute accent}ttle N., and Hodnett B.K. The catalytic oxidation of ammonia: influence of water and sulfur on selectivity to nitrogen over promoted copper oxide/alumina catalysts. Catal. Today 55 (2000) 189-195
17. 2. Catal. Today 61 (2000) 187-195
18. 3 catalysts. Ind. Eng. Chem. Res. 39 (2000) 3694-3697
19. 3. Chem. Eng. Sci. 59 (2004) 4113-4123
20. Lou J.C., and Chen C.L. Destruction of butanone and toluene with catalytic incineration. Hazard. Waste Hazard. Mater. 12 (1995) 37-49
21. Lou J.C., and Lee S.S. Destruction of trichloromethane with catalytic oxidation. Appl. Catal. B: Environ. 12 (1997) 111-123
22. Lou J.C., and Lee S.S. Kinetics study of trichloromethane with catalysis. J. Chin. Inst. Environ. Eng. 5 (1995) 301-307
23. Gangwal S.K., Mullins M.E., Spivey J.J., and Caffrey P.R. Kinetics and selectivity of deep catalytic oxidation of n-hexane and benzene. Appl. Catal. 36 (1988) 231-247
24. Richardson J.T. Principles of Catalyst Development (1989), Plenum Press, New York
25. Satterfield C.N. Heterogeneous Catalysis in Industrial Practice (1991), McGraw-Hill, New York
26. Mars P., and van Krevelen D.W. Oxidation carried out by means of vanadium oxide catalysts. Chem. Eng. Sci. 3 (1954) 41-59
27. 3 catalyst. Chemosphere 61 (2005) 469-477
28. Carvalho M.C.N.A., Passos F.B., and Schmal M. The behavior of Cu/ZSM-5 in the oxide and reduced form in the presence of NO and methanol. Appl. Catal. A: General 193 (2000) 265-276
29. 3 catalysts: influence of catalyst preparation method. Appl. Catal. B: Environ. 23 (1999) 259-269
30. Barresi A.A., and Baldi G. Deep catalytic oxidation kinetics of benzene-ethenylbenzene mixtures. Chem. Eng. Sci. 47 (1992) 1943-1953
31. 3 on Pd and Ir comparison with Pt and Rh. J. Mol. Catal. A: Chem. 120 (1997) 165-171
32. Trombetta M., Ramis G., Busca G., Montanari B., and Vaccari A. Ammonia adsorption and oxidation on Cu/Mg/Al mixed oxide catalysts prepared via hydrotalcite-type precursors. Langmuir 13 (1997) 4628-4637
33. Budhi Y.W., Jaree A., Hoebink J.H.B.J., and Schouten J.C. Simulation of reverse flow operation for manipulation of catalyst surface coverage in the selective oxidation of ammonia. Chem. Eng. Sci. 59 (2004) 4125-4135
34. Boisen A., Dahl S., Nørskov J.K., and Christensen C.H. Why the optimal ammonia synthesis catalyst is not the optimal ammonia decomposition catalyst. J. Catal. 230 (2005) 309-312
35. Hannevold L., Nilsen O., Kjekshus A., and Fjellvåg H. Reconstruction of platinum-rhodium catalysts during oxidation of ammonia. Appl. Catal. A: General 284 (2005) 163-176