Feasibility study of the oxidative dehydrogenation of ethane in an electrochemical packed-bed membrane reactor

Industrial and Engineering Chemistry Research

Volumn 46, Issue 25, 2007, Pages 8665-8673

  Chalakov, Lyubomir ^a   Rihko Struckmann, Liisa K ^b   Munder, Barbara ^b   Sundmacher, Kai ^a,b  

^a OTTO VON GUERICKE UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTORS; DEHYDROGENATION; ELECTROCHEMISTRY; PACKED BEDS;

OXIDATIVE DEHYDROGENATION; OXYGEN-ION CONDUCTION;

ETHANE;

CHEMICAL REACTORS; DEHYDROGENATION; ELECTROCHEMISTRY; ETHANE; PACKED BEDS;

EID: 37249027737     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie070089i     Document Type: Conference Paper

References (25)

1. Cavani, F.; Trifiro, F. Selective Oxidation of Light Alkanes: Interaction between the Catalyst and the Gas Phase on Different Classes of Catalytic Materials. Catal. Today 1999, 51, 561.
2. Klose, F.; Wolff, T.; Thomas, S.; Seidel-Morgenstern, A. Concentration and Residence Time Effects in Packed Bed Membrane Reactors. Catal. Today 2003, 52, 25.
3. Banares, M. A. Supported Metal Oxide and Other Catalysts for Ethane Conversion: A Review. Catal. Today 1999, 51, 319.
4. Solsona, B.; Zazhigalov, V. A.; Lopez, Nieto, J. M.; Bacherikova, I. V.; Diyuk, E. A. Oxidative Dehydrogenation of Ethane on Promoted VPO Catalysts. Appl. Catal. A: Gen. 2003, 249, 81.
5. Gaab, S.; Machli, M.; Find, J.; Grasselli, R. K.; Lercher, J. A. Oxidative Dehydrogenation of Ethane over Novel Li/Dy/Mg Mixed Oxides: Structure-Activity Study. Top. Catal. 2003, 23 (1-4), 151.
6. Bodke, A. S.; Olschki, D. A.; Schmidt, L. D.; Ranzi, E. High Selectivities to Ethylene by Partial Oxidation of Ethane. Science 1999, 255, 712.
7. Sanchez Marcano, J. G.; Tsotsis, T. T. Catalytic Membranes and Membrane Reactors; Wiley-VCH: New York, 2002.
8. Klose, F.; Wolff, T.; Thomas, S.; Seidel-Morgenstern, A. Operation Modes of Packed-Bed Membrane Reactors in the Catalytic Oxidation of Hydrocarbons. Appl Catal. A: Gen. 2004, 257, 193.
9. Coronas, J.; Menendez, M.; Santamaria, J. Use of a Ceramic Membrane Reactor for the Oxidative Dehydrogenation of Ethane to Ethylene and Higher Hydrocarbons. Ind. Eng. Chem. Res. 1995, 34, 4229.
10. Tonkovich, A. L. Y.; Zika, J. L.; Jimenes, D. M.; Roberts, G. L.; Cox, J. L. Experimental Investigations of Inorganic Membrane Reactors: A Distributed Feed Approach for Partial Oxidation Reactions. Chem. Eng. Sci. 1996, 51 (5), 789.
11. Rebeilleau-Dassonneville, M.; Rosini, S.; van Veen, A. C.; Farrusseng, D.; Mirodatos, C. Oxidative Activation of Ethane on Catalytic Modified Dense Ionic "Oxygen Conducting Membranes. Catal. Today 2005, 104, 131.
12. Wang, H. H.; Cong, Y.; Yang, W. High Selectivity of Oxidative Dehydrogenation of Ethane to Ethylene in an Oxygen Permeable Membrane Reactor. Chem. Commun. 2002, 14, 1468.
13. Wang, H. H.; Cong, Y.; Yang, W. Continuous Oxygen Ion Transfer Medium as a Catalyst for High Selective Oxidative Dehydrogenation of Ethane. Catal. Lett. 2002, 54, 101.
14. Akin, F. T.; Lin, Y. S. Selective Oxidation of Ethane to Ethylene in a Dense Tubular Membrane Reactor. J. Membr. Sci. 2002, 209, 457.
15. Sundmacher, K.; Rihko-Struckmann, L.; Galvita, V. Solid Electrolyte Membrane Reactors: Status and Trends. Catal. Today 2005, 104, 185.
16. York, A. P. E.; Hamakawa, S.; Hayakawa, T.; Sato, K.; Tsunoda, T.; Takehira, K. Partial Oxidation of C2-C4 Alkanes into Oxygenates Using an Au|Yttria-Stabilized Zirconia|Ag Electrochemical Reaction Cell. J. Chem. Soc., Faraday Trans. 1996, 92 (19), 3579.
17. Hamakawa, S.; Sato, K.; Hayakawa, T.; York, A. P. E.; Tsunoda, T.; Suzuki, K.; Shimizu, M.; Takehira, K. Selective Oxidation of Ethane Using the Au|YSZ|Ag Electrochemical Membrane System. J. Electrochem. Soc. 1997, 144 (1), 1.
18. 5 Supported on a YSZ-Aided Membrane Reactor. Appl. Catal. A: Gen. 2004, 273, 133.
19. Munder, B.; Rihko-Struckmann, L.; Sundmacher, K. Steady-state and forced-periodic operation of solid electrolyte membrane reactors for selective oxidation of n-butane to maleic anhydride. Chem. Eng. Sci. 2007, in press.
20. Ramos, R.; Menéndez, M.; Santamaria, J. Oxidative Dehydrogenation of Propane in an Inert Membrane Reactor. Catal. Today 2000, 56, 239.
21. Bielanski, A.; Haber, J. Oxygen in Catalysis; Marcel Dekker: New York, 1991.
22. Ye, Y.; Rihko-Struckmann, L.; Munder, B.; Sundmacher, K. Partial Oxidation of n-Butane in a Solid Electrolyte Membrane Reactor: Periodic and Steady-State Operations. Appl. Catal. A: Gen. 2005, 255 (1-2), 86.
23. Ye, Y.; Rihko-Struckmann, L.; Munder, B.; Sundmacher, K. Partial Oxidation of n-Butane in a Solid Electrolyte Membrane Reactoi-Influence of Electrochemical Oxygen Pumping. J. Electrochem. Soc. 2006, 153 (2), D21.
24. Ye, Y.; Rihko-Struckmann, L.; Munder, B.; Rau, H.; Sundmacher, K. Feasibility of an Electrochemical Membrane Reactor for the Partial Oxidation of n-Butane to Maleic Anhydride. Ind. Eng. Chem. Res. 2004, 43, 4551.
25. 3Preparation, Characterization and Reactivity. Catal. Today 2004, 96, 179.