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The stereochemistries of the sugars in all the structures were assigned by comparison of their 1H and 13C NMR data with literature data. The protons and carbons of an L-sugar linked to a chiral aglycone will have slightly different 1H and 13C NMR chemical shifts than those of a D-sugar, as indicated by comparison of the 1H NMR spectra of (R, and (S)-2-butanol linked to D-glucose (Seroka, P, Plosiñski, M, Czub, J, Sowiñski, P, Pawlak, J. Magn. Reson. Chem. 2006, 44, 132-138, The close matching of our NMR data with literature data for a similar D-glucopyranosyl-(1→4)-β-D-digitalopyranoside thus provides strong inferential evidence of the assigned stereochemistry
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