Multiple bonds between transition metals and 'bare' main group elements. A reactive manganese-tellurium-manganese framework: Synthesis, structure, and alkylidene addition

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 11, 1984, Pages 686-687

  Herrmann, Wolfgang A ^a   Hecht, Christian ^a   Ziegler, Manfred L ^b   Balbach, Barbara ^b  

^a GOETHE UNIVERSITY   (Germany)

^b UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049110755     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39840000686     Document Type: Article

References (16)

1. W. A. Herrmann,Adv. Organomet. Chem.,1982, 20, 159;
2. W. A. Herrmann, J. Organomet. Chem.,1983, 250, 319;
3. F. G. A. Stone, Angew. Chem., Int. Ed. Eng.,1984, 23, 89.
4. Another useful synthetic strategy has been developed by Knox etal., cf.A. F. Dyke, S. R. Finnimore, S. A. R. Knox, P. J. Naish, A. G. Orpen, G. H. Riding, and G. E. Taylor, in ‘Reactivity of Metal-Metal Bonds,’ ed. M. H. Chisholm, ACS Symposium Series, vol. 155, p. 259, American Chemical Society, Washington, D.C., 1981.
5. Review: W. A. Herrmann, ‘Small Hydrocarbons as Bridging Ligands in Transition Metal Chemistry: Synthesis, Structures, and Reactivity,’ in ‘Organometallic Compounds,’ ed. B. L. Shapiro, vol. 1, p. 383 ff., Texas A & M University Press, College Station, Texas, U.S.A., 1983.
6. Bare oxygen and nitrogen atoms exhibiting multiple bonding to transition metals are hitherto largely confined to complexes with the metal atoms in higher oxidation states,cf.F. A. Cotton and G. Wilkinson, ‘Advanced Inorganic Chemistry,’ Fourth Edition, Chap. 4, Wiley & Sons, New York 1980.
7. Recent examples: G. Huttner, B. Sigwarth, J. v. Seyerl, and L.Zsolnai,Chem. Ber.,1982, 115, 2035;
8. H. Lang, L. Zsolnai, and G. Huttner,Agnew. Chem., Int. Ed. Engl.,1983, 22, 976;
9. H. Lang, L. Zsolnai, and G. Huttner, Angew. Chem. Suppl.,1983, 1451.
10. M. Herberhold, D. Reiner, and U. Thewalt, manuscript in preparation (M. Herberhold, personal communication).
11. I. Bernal, M. Creswick, and W. A. Herrmann, Z.Naturforsch., TeilB,1979, 34, 1345.
12. A. F. Wells, ‘Structural Inorganic Chemistry,’ Fourth Edition, Clarendon Press, Oxford, 1975.
13. M. Herberhold, D. Reiner, and D. Neugebauer,Angew. Chem., Int. Ed. Engl.,1983, 22, 59;
14. M. Herberhold, D. Reiner, and D. Neugebauer, Angew. Chem. Suppl.,1983, 10
15. W. A. Herrmann, J. Weichmann, R. Serrano, K. Blech-schmitt, H. Pfisterer, and M. L. Ziegler,Angew. Chem., Int. Ed. Engl.,1983, 22, 314;
16. W. A. Herrmann, J. Weichmann, R. Serrano, K. Blech-schmitt, H. Pfisterer, and M. L. Ziegler, Angew. Chem. Suppl.,1983, 363.