Synthesis and x-ray structural characterization of the centred icosahedral gold cluster compound [Au13(PMe2Ph)10Cl 2](PF6)3; the realization of a theoretical prediction

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 5, 1981, Pages 201-202

  Briant, Clive E ^a   Theobald, Brian R C ^a   White, James W ^a   Bell, Linda K ^a   Mingos, D Michael P ^a   Welch, Alan J ^b  

^a UNIVERSITY OF OXFORD   (United Kingdom)

^b CITY UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049109780     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39810000201     Document Type: Article

References (9)

1. D. M. P. Mingos, J. Chem. Soc, Dalton Trans., 1976, 1163.
2. F. A. Vollenbroek, P. C. P. Bouten, J. M. Trousten, J. P. van den Berg, and J. J. Bour, Inorg. Chem., 1978, 17, 1345.
3. F. Cariati and N. Naldini, Inorg. Chim. Acta, 1971, 5, 172; L. Malatesta, Gold Bull., 1975, 8, 48.
4. M. T. Anthony, M. L. H. Green, and D. Young, J. Chem. Soc, Dalton Trans., 1975, 1419.
5. P. L. Bellon, F. Cariati, M. Manaserro, L. Naldini, and M. Sansoni, Chem. Commun., 1971, 1423.
6. P. Bellon, M. Manaserro, and M. Sansoni, J. Chem. Soc, Dalton Trans., 1972, 1481.
7. 4 [dppm = bis (diphenylphosphino) methane] which appears to have an icosahedral cluster unit. However, crystallographic disorder and the possibility that the unit cell contains a second unidentified cluster compound have limited the characterization of this compound.
8. V. G. Albano, A. Cariatti, P. Chini, G. Ciani, S. Martinego, and W. M. Anker, J. Chem. Soc, Chem. Commun., 1975, 859.
9. 12 as ortho, meta, and para.