Temperature and pressure effects on surface processes at noble metal electrodes. Part 1. - Entropy of chemisorption of H at Pt surfaces

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Volumn 74, Issue , 1978, Pages 1373-1389

  Conway, Brian E ^a   Angerstein Kozlowska, Halina ^a   Sharp, William B A ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049109125     PISSN: 03009599     EISSN: None     Source Type: Journal    
DOI: 10.1039/F19787401373     Document Type: Article

References (41)

1. J. W. Scbultze, Electrochim. Acta, 1976, 21, 327.
2. F. G. Will and C. A. Knorr, Z. Elektrochem., 1960, 64, 258.
3. B. E. Conway, H. Angerstein-Kozlowska and W. B. A. Sharp, in Proc. Symposium on Electrocatalysis, ed. M. Breiter (The Electrochemical Society, 1974), p. 94.
4. W. J. Lorenz, H. D. Hermann, N. Wüthrich and F. Hilbert, J. Electrochem. Soc., 1974, 121, 1167.
5. V. S. Bagotskii, Y. B. Vasiliev and I. I. Pyshnograeva, Electrochim. Acta, 1971, 16, 2141.
6. F. G. Will, J. Electrochem. Soc., 1965, 112, 451.
7. A. N. Frumkin and B. Slygin, Acta Physiochim. U.R.S.S., 1936, 5, 819.
8. A. N. Frumkin, N. A. Balashova and V. E. Kazarinov, J. Electrochem. Soc., 1966, 113, 1011.
9. R. Woods, J. Electroanalyt. Chem., 1974, 49, 317.
10. J. W. Schultze, Ber. Bunsenges. phys. Chem., 1969, 73, 483.
11. V. S. Bagotskii, Y. B. Vasiliev, J. Weber and J. N. Pirtskhaleva, J. Electroanalyt. Chem., 1970, 27, 31.
12. W. Boeld and M. W. Breiter, Electrochim. Acta, 1961, 5, 145, 169.
13. R. V. Marvet and O. A. Petrii, Elektrokhimiya, 1965, 1, 1225.
14. N. Golyanitskaya, A. A. Sutyagina and G. D. Vovchenko, Russ. J. Phys. Chem., 1973, 47, 382.
15. S. Schuldiner and T. B. Warner, J. Electrochem. Soc., 1965, 112, 212.
16. B. I. Podlovschenko and E. A. Kolyadko, Electrokhimiya, 1972, 8, 1140.
17. B. E. Conway, H. Angerstein-Kozlowska, W. B. A. Sharp and E. E. Criddle, Analyt. Chem., 1973, 45, 1331.
18. B. E. Conway, Proc. Roy. Soc. A, 1960, 256, 128.
19. S. Gottesfeld and B. E. Conway, J.C.S. Faraday I, 1974, 70, 1793.
20. S. Schuldiner, B. Rosen and D. R. Flinn, J. Electrochem. Soc., 1972,119, 412.
21. T. Biegler, D. A. J. Rand and R. Woods, J. Electroanalyt. Chem., 1971, 29, 269.
22. S. B. Brummer, J. Ford and M. J. Turner, J. Phys. Chem., 1965, 69, 562, 3424.
23. B. E. Conway, H. Angerstein-Kozlowska and H. P. Dhar, Electrochim. Acta, 1974, 19, 455.
24. J. Klinger, Ph.D. Thesis (University of Ottawa, 1966), in press.
25. A. N. Frumkin and O. A. Petrii, Electrochim. Acta, 1970, 15, 391.
26. H. Angerstein-Kozlowska and B. E. Conway, J. Electroanalyt. Chem., in press.
27. B. E. Conway and J. O’M. Bockris, Modern Aspects of Electrochemistry (Butterworth, London, 1954), vol. 1, chap. 2.
28. F. H. Lee and Y. K. Tai, J. Chinese Chem. Soc., 1941, 8, 60.
29. J. M. Crockford and A. Hall, J. Phys. Chem., 1950, 54, 731.
30. J. E. B. Randles and D. Schiffrin, J. Electroanalyt. Chem., 1965, 10, 480.
31. E.g. see J. E. Desnoyers and C. Joliecoeur, Modern Aspects of Electrochemistry, ed. J. O’M. Bockris and B. E. Conway (Plenum, N.Y., 1969), vol. 5, p. 1.
32. E. McCafferty and A. C. Zettlemoyer, Disc. Faraday Soc., 1971, 52, 239.
33. F. C. Ho and B. E. Conway, in press; this work demonstrates, from reflectivity measurements, that the more weakly bound H at Pt behaves similarly to H at Pd that has had time to diffuse into the surface region of the metal.
34. J. M. Basset, A. Theolier, M. Primet and M. Prettre, Proc. 5th Int. Congress on Catalysis (North Holland, 1972).
35. B. E. Conway, Elektrokhimiya, Frumkin memorial issue, 1977, 12(6), 822.
36. F. P. Bowden, Nature, 1928, 122, 647.
37. J. D. Pearson and J. A. V. Butler, Trans. Faraday Soc., 1938, 34, 1163.
38. M. W. Breiter, Electrochim. Acta, 1962, 7, 25.
39. M. W. Breiter, Ann. N. Y. Acad. Sci., 1963,101, 709.
40. S. Gilman, in Electroanalytical Chemistry, ed. A. J. Bard (Arnold, N.Y., 1967), vol. 2, p. 111.
41. A. Eucken and B. Weblus, Z. Elektrochem., 1951, 55, 114.