Double carbonylation of substituted benzyl chlorides with cobalt carbonyl anion by phase transfer catalysis to give arylpyruvic acids

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 24, 1978, Pages 1090-1091

  Des Abbayes, Hervé ^a   Buloup, Anne ^a  

^a Inst de Recherche Contre le Cancer   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049102278     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39780001090     Document Type: Article

References (11)

1. T. A. Weil, L. Cassar, and M. Foa, ‘Organic Synthesis via Metal Carbonyls,’ vol. II, Wiley, New York, 1977, p. 517.
2. R. F. Heck, Adv. Catalysis, 1977, 26, 323.
3. H. des Abbayes and H. Alper, J. Amer. Chem. Soc., 1977, 99, 98.
4. H. Alper, H. des Abbayes, and D. des Roches, J. Organometallic Chem., 1976, 121, C31.
5. H. Alper and H. des Abbayes, J. Organometallic Chem., 1977, 134, C11.
6. L. Cassar and M. Foa, J. Organometallic Chem., 1977, 134, C15.
7. A recent review on carbon monoxide insertion (A. Wojcicki, Adv. Organometallic Chem., 1973, 11, 87) does not report any example of double CO insertion, except in a speculative mechanism (p. 106).
8. 5- anion, and was found to have a high kinetic stability (C. P. Casey, C. A. Bunnell, and J. C. Calabresse, J. Amev. Chem. Soc., 1976, 98, 1166).
9. 2Br, fortuitously observed in our study on the carbonylation of benzyl bromides L. Cassar and M. Foa, J. Organometallic Chem., C15.
10. Z. Nagy-Magos, G. Bor, and L. Marko, J. Organometallic Chem., 1968, 14, 205.
11. E. V. Dehmlow, Angew. Chem. Internat. Edn., 1977, 16, 493.