Unstable intermediates in the gas-phase. Formation of thioformaldehyde from trithiolan

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 8, 1977, Pages 287-288

  Bock, H ^a   Solouki, B ^a   Mohmand, S ^a   Block, E ^a   Revelle, L K ^b  

^a GOETHE UNIVERSITY   (Germany)

^b UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049099557     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39770000287     Document Type: Article

References (15)

1. H. Bock, T. Hirabayashi, S. Mohmand, and B. Solouki, Angew. Chem., 1977, 89, 106;
2. H. Bock, T. Hirabayashi, S. Mohmand, and B. Solouki Angew. Chem.Internat. Edn., 1977, 16, 105.
3. M.W. Sinclair, J. C. Ribes, N. Fourilds, R. C. Brown, and P. D. Godfrey, Int. Astron. Union Circ., No. 2362, Nov. 1971.
4. D.R. Johnson, F. X. Powell, and W. H. Kirchoff, J. Mol. Spectroscopy, 1971, 39, 136;
5. J. W. C. Johns and W. B. Olson, J. Mol. Spectroscopy., p. 479;
6. M. E. Jacox and D. E. Milligan, J. Mol. Spectroscopy., 1975, 58, 142;
7. H. W. Kroto and R. J. Suffolk, Chem. Phys. Letters, 1972, 15, 545.
8. E. Block, H. Bock, S. Mohmand, P. Rosmus, and B. Solouki, Angew Chem., 1976, 88, 380;
9. E. Block, H. Bock, S. Mohmand, P. Rosmus, and B. Solouki Angew. Chem. Internat. Edn., 1976, 15, 383.
10. B. Solouki, P. Rosmus, and H. Bock, J. Amer. Chem. Soc., 1976, 98, 6054.
11. Cf.e.g. H. Bock and S. Mohmand, Angew. Chem., 1977, 89, 105;
12. Cf.e.g. H. Bock and S. Mohmand Angew. Chem. Internat. Edn., 1977, 16, 104.
13. E. Block, R. E. Penn, R. J. Olsen, and P. F. Sherwin. J. Amer. Chem. Soc., 1976, 98, 1264.
14. We have found'that this antibacterial component of the red alga Chondria californica (S. J. Wratten and D. J. Faulkner, J. Org. Chem., 1976, 41, 2465) can be conveniently prepared in pure form in 60% yield by oxidation at — 30°Cof a tetrahydrofuran- BulOH solution of 1,2,4-trithiolan with 6% H202 in BulOH in the presence of a catalytic quantity of V2Os
15. F. E. Hardy, P. R. H. Speakman, and P. Rubson, J. Chem. Soc. (C), 1969, 2334.