Trapping of radicals by dialkyl phosphite ions; synthesis of α-nitroalkylphosphonates by SRN1 reactions

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 5, 1980, Pages 216-217

  Russell, Glen A ^a   Hershberger, James ^a  

^a IOWA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049094658     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39800000216     Document Type: Article

References (10)

1. J F Bunnett Accounts Chem Res1978, 11 413.
2. G A Russell and J Hershberger submitted to J Amer Chem Soc.
3. G A Russell, J Hershberger and K Owens J Amer Chem Soc1979 101 1312.
4. This assignment is consistent with e s r investigations of PhP(OR)s (G Boekestem, E H J M Jansen and H M Buck JCS Chem Comm1974 118.
5. A G Davies M J Parrott and B P Roberts JCS Chem Commp 973) and R2C=CHP(OR)3 radicals.
6. J VBaban, C J Cooksey and B P Roberts JCS Perkin II1979 781 which indicate that the unpaired electron is associated with the phenyl or vinyl group rather than localized at the phosphorus atom A similar conclusion was reached in regard to the radical anions of PhPO(OH) and PhPO(OH)2.
7. S P Mishra and M C R Symons Tetrahedron Letters1973 4061.
8. S P Mishra and M C R Symons JCS Chem Comm1974, 606.
9. S P Mishra and M C R Symons JCS Perkin II1976 21.
10. a Nitroalkylphosphonates have not been extensively imestigated The synthesis of (EtO)2P(O)CMe2NO2 by the permanganate oxidation of the ammo compound has been reported (K A Petrov, V A Chauzov, L V Pastukhova and W N Bogdanov, Zhur obshchei Khim, 1976, 46, 1246).