Preparation of cationic (E)-σ-alkenyl palladium complexes having a P-O-N or a P-O-P tridentate ligand as a stabilized intermediate of palladium-catalysed stereoselective addition of methanol to acetylenes; Characterisation, X-ray analysis and the reaction pathway

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 20, 1995, Pages 2099-2100

  Kataoka, Yasutaka ^a   Tsuji, Yasuyuki ^a   Matsumoto, Osamu ^a   Ohashi, Masataka ^a   Yamagata, Tsuneaki ^a   Tani, Kazuhide ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049087271     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39950002099     Document Type: Article

References (23)

1. P.M. Maitlis, P. Espinet, M.J.H. Russell, Comprehensive Organometallic Chemistry, 1982, ed. G. Wilkinson, F. G. A. Stone, E. W. Abel, Pergamon, Oxford vol. 6, 38. 9
2. Y. Tohda, K. Sonogashira and N. Hagihara, J. Chem. Soc., Chem. Commun., 1975, 54
3. H.C. Clark, C.R. Milne and C.S. Wong, J. Organomet. Chem., 1977, 136, 265
4. T. Yasuda, Y. Kai, N. Yasuoka and N. Kasai, Bull. Chem. Soc. Jpn., 1977, 50, 2888
5. H.C. Clark and C.R. Milne, J. Organomet. Chem., 1978, 161, 51, The X-ray crystal structure of an (E)-σ-alkenyl platinum complex has been reported, see;, Concrete examples for trans addition of a nucleophile to the coordinated alkyne to produce (E)-σ-alkenyl complexes have been indicated for molybdenum and iron complexes:
6. M.H. Chisholm and H.C. Clark, Inorg. Chem., 1971, 10, 2557
7. M.H. Chisholm and H.C. Clark, J. Am. Chem. Soc., 1972, 94, 1532
8. M.H. Chisholm and H.C. Clark, Acc. Chem. Res., 1973, 6, 202
9. D.L. Reger, S.A. Klaeren and L. Lebioda, Oganometallics, 1986, 5, 1072
10. A. Albinati, P.S. Pregosin and R. Rüedi, Helv. Chim. Acta, 1985, 68, 2046
11. P.M. Maitlis, The Organic Chemistry of Palladium, 1971, 2, 47, 58Academic, New York
12. P.M. Maitlis, Acc. Chem. Res., 1976, 9, 93
13. T.R. Jack, C.J. May and J. Powell, J. Am. Chem. Soc., 1977, 99, 4707
14. A. Avshu, R.D. O'Sullivan and A.W. Parkins, J. Chem. Soc., Dalton Trans., 1983, 1619
15. Y. Kataoka, O. Matsumoto, M. Ohashi, Y. Yamagata and K. Tani, Chem. Lett., 1994, 1283
16. D.L. Reger, K.A. Belmore, E. Mintz, N.G. Charles, E.A.H. Griffith and E.L. Amma, Organometallics, 1983, 2, 101
17. D.L. Reger, K.A. Belmore, E. Mintz and P.J. McElligott, Organometallics, 1984, 3, 134
18. D.L. Reger, S.A. Klaeren and L. Lebioda, Organometallics, 1986, 5, 1072
19. F. Canziani, L. Garlaschelli and M.C. Malatesea, J. Organomet. Chem., 1978, 146, 179
20. M. Yabuta, S. Nakamura, T. Yamagata and K. Tani, Chem. Lett., 1993, 323
21. K. Tani, M. Yabuta, S. Nakamura and T. Yamagata, J. Chem. Soc., Dalton Trans., 1993, 2781
22. K. Tani, S. Nakamura, T. Yamagata and Y. Kataoka, Inong. Chem., 1993, 32, 5398
23. J.E. Huheey, Inorganic Chemistry, 1983, 258, 2593rd edn. Harper & Row, New York