Stereoselective synthesis of (Rp)-benzylphenyl-[2-(S)- bromomethylpyrrolidine-1-yl]phosphine oxide from (S)-(+)-prolinol by the Michaelis-Arbuzov reaction: Application in the synthesis of a chiral hybrid phosphine-phosphine oxide ligand

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 12, 1989, Pages 805-807

  Faure, Bruno ^a   Archavlis, Albert ^a   Buono, Gérard ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049085789     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39890000805     Document Type: Article

References (6)

1. ‘Asymmetric Synthesis,’ vol. 5, ‘Chiral Catalysis,’ ed. J. D. Morisson, Academic Press, New York, 1985
2. H. B. Kagan, ‘Comprehensive Organometallic Chemistry,’ eds. G. Wilkinson, F. G. A. Stone, and E. W. Abel, Pergamon Press, Oxford, 1982, Vol. 8, p. 463.
3. W. J. Richter, Chem. Ber., 1984, 117, 2328.
4. P. Cros, G. Buono, G. Peiffer, D. Denis, A. Mortreux, and F. Petit, Nouv. J. Chem., 1987, 11, 573.
5. C. F. Hammer and J. D. Weber, Tetrahedron, 1981, 37, 2173.
6. In the Grignard cross coupling reaction using (R)-t-Leuphos as ligand, the aminofunction of the ligand is co-ordinated to the magnesium atom of the Grignard reagent aiding the enantioselec-tion: T. Hayashi and M. Kumada, Acc. Chem. Res., 1982, 15, 385.