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84943050868
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Interbond angles in three-coordinate bismuth(III) compounds are usually in the range 92—102°. This reflects a predominance of p character in the bonding orbitals and a correspondingly large degree of s character in the lone pair. Three-coordinate bismuth is therefore less Lewis basic than its lighter congeners
-
Interbond angles in three-coordinate bismuth(III) compounds are usually in the range 92—102°. This reflects a predominance of p character in the bonding orbitals and a correspondingly large degree of s character in the lone pair. Three-coordinate bismuth is therefore less Lewis basic than its lighter congeners.
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15
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18
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0001214227
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For examples of these types of complex, see
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For examples of these types of complex, see: L. D. Hutchins, H.-U. Reisacher, G. L. Wood, E. N. Duesler, and R. T. Paine, J. Organomet. Chem., 1987, 335, 229.
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84985532375
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E. Gross, K. Jorg, K. Fiederling, A. Gottlein, W. Malisch, and R. Boese, Angew. Chem., Int. Ed. Engl., 1984, 23, 738.
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22
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84943078356
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An interesting comparison can be made between (5) and the tris dithiocarbamate complex, Bi{S2CNEt2}3. The structure of the latter complex has been determined by T-ray methods and involves six-coordinate bismuth(m), the dithiocarbamate ligands being bidentate as observed in (5)
-
An interesting comparison can be made between (5) and the tris dithiocarbamate complex, Bi{S2CNEt2}3. The structure of the latter complex has been determined by T-ray methods and involves six-coordinate bismuth(m), the dithiocarbamate ligands being bidentate as observed in (5);
-
-
-
-
24
-
-
84943074014
-
-
Such compounds have been described as containing ‘bare’ main group elements, see reference 1a
-
Such compounds have been described as containing ‘bare’ main group elements, see reference 1a.
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25
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F. G. A. Stone, ibid., 1984, 23, 89.
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51
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84943068801
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-
The type of compounds implied here are of the general formula {MLn}2 ER, (E = P, As, Sb; ML„ is a 16-electron fragment such as Cr(CO)5 or Mn(CO)2(C5H5)
-
The type of compounds implied here are of the general formula {MLn}2 ER, (E = P, As, Sb; ML„ is a 16-electron fragment such as Cr(CO)5 or Mn(CO)2(C5H5).
-
-
-
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52
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0022046841
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For reviews on this area of chemistry see
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For reviews on this area of chemistry see: G. Huttner, Pure Appl. Chem., 1986, 58, 585.
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