메뉴 건너뛰기




Volumn 17, Issue , 1988, Pages 269-281

Meldola Medal lecture. Organotransition metal complexes incorporating bismuth

Author keywords

[No Author keywords available]

Indexed keywords


EID: 37049082150     PISSN: 03060012     EISSN: None     Source Type: Journal    
DOI: 10.1039/CS9881700269     Document Type: Conference Paper
Times cited : (40)

References (58)
  • 13
    • 84943050868 scopus 로고    scopus 로고
    • Interbond angles in three-coordinate bismuth(III) compounds are usually in the range 92—102°. This reflects a predominance of p character in the bonding orbitals and a correspondingly large degree of s character in the lone pair. Three-coordinate bismuth is therefore less Lewis basic than its lighter congeners
    • Interbond angles in three-coordinate bismuth(III) compounds are usually in the range 92—102°. This reflects a predominance of p character in the bonding orbitals and a correspondingly large degree of s character in the lone pair. Three-coordinate bismuth is therefore less Lewis basic than its lighter congeners.
  • 22
    • 84943078356 scopus 로고    scopus 로고
    • An interesting comparison can be made between (5) and the tris dithiocarbamate complex, Bi{S2CNEt2}3. The structure of the latter complex has been determined by T-ray methods and involves six-coordinate bismuth(m), the dithiocarbamate ligands being bidentate as observed in (5)
    • An interesting comparison can be made between (5) and the tris dithiocarbamate complex, Bi{S2CNEt2}3. The structure of the latter complex has been determined by T-ray methods and involves six-coordinate bismuth(m), the dithiocarbamate ligands being bidentate as observed in (5);
  • 24
    • 84943074014 scopus 로고    scopus 로고
    • Such compounds have been described as containing ‘bare’ main group elements, see reference 1a
    • Such compounds have been described as containing ‘bare’ main group elements, see reference 1a.
  • 33
    • 0021371679 scopus 로고
    • ibid
    • F. G. A. Stone, ibid., 1984, 23, 89.
    • (1984) , vol.23 , pp. 89
    • Stone, F.G.A.1
  • 51
    • 84943068801 scopus 로고    scopus 로고
    • The type of compounds implied here are of the general formula {MLn}2 ER, (E = P, As, Sb; ML„ is a 16-electron fragment such as Cr(CO)5 or Mn(CO)2(C5H5)
    • The type of compounds implied here are of the general formula {MLn}2 ER, (E = P, As, Sb; ML„ is a 16-electron fragment such as Cr(CO)5 or Mn(CO)2(C5H5).
  • 52
    • 0022046841 scopus 로고
    • For reviews on this area of chemistry see
    • For reviews on this area of chemistry see: G. Huttner, Pure Appl. Chem., 1986, 58, 585.
    • (1986) Pure Appl. Chem. , vol.58 , pp. 585
    • Huttner, G.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.