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Volumn , Issue 19, 1995, Pages 1957-1958

Boron-centred diradical dianion: A new triplet state molecule

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EID: 37049074952     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39950001957     Document Type: Article
Times cited : (35)

References (27)
  • 5
    • 4243542678 scopus 로고
    • For a review on ion pairing in organic dianions, see:, Diborane 1 is recovered upon quenching with iodine., Further studies are needed to unambigously assign the spin multiplicity of the ground state; e. g. magnetisation studies in ref. 6., CV studies for an isomer of diborane 1, bis(dimesitylboron)-1,4-phenyl-ene and dimesitylphenylborane (DMF-TBAP, carbon glass electrode):, All potentials are given in THF-TBAP at 100 µm Pt-disk working electrode, with ferrocene (0.510 V vs. SCE) as reference, at ambient temp.; see:, Dimesitylboron fluoride:, references 3(b) and 3(c)., The diradical dianion of diborane 1 is π-isoelectronic with Schlenk hydrocarbon, a diradical of which derivatives have been shown to possess S= 1 ground state:, magnetic susceptibility, UV-VIS spectroscopy, ion pairing,, electrochemistry,, magnetic resonance spectroscopy,, X-ray crystallography, Trimesitylboron radical anions:, and references therein.
    • A. Rajca, Chem. Rev., 1994, 94, 871, For a review on ion pairing in organic dianions, see:, Diborane 1 is recovered upon quenching with iodine., Further studies are needed to unambigously assign the spin multiplicity of the ground state; e. g. magnetisation studies in ref. 6., CV studies for an isomer of diborane 1, bis(dimesitylboron)-1,4-phenyl-ene and dimesitylphenylborane (DMF-TBAP, carbon glass electrode):, All potentials are given in THF-TBAP at 100 µm Pt-disk working electrode, with ferrocene (0.510 V vs. SCE) as reference, at ambient temp.; see:, Dimesitylboron fluoride:, references 3(b) and 3(c)., The diradical dianion of diborane 1 is π-isoelectronic with Schlenk hydrocarbon, a diradical of which derivatives have been shown to possess S= 1 ground state:, magnetic susceptibility, UV-VIS spectroscopy, ion pairing,, electrochemistry,, magnetic resonance spectroscopy,, X-ray crystallography, Trimesitylboron radical anions:, and references therein.
    • (1994) Chem. Rev. , vol.94 , pp. 871
    • Rajca, A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.