Preparation and characterization of a four-coordinated ditellurane stabilized by a transannular Tellurium-Tellurium bond from 1,5-ditelluracyclooctane: A new multicentre hypervalent species

Journal of the Chemical Society, Perkin Transactions 1

Volumn , Issue 20, 1992, Pages 2583-2584

  Fujihara, Hisashi ^a   Takaguchi, Yutaka ^a   Ninoi, Takeshi ^a   Erata, Tomoki ^a   Furukawa, Naomichi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049071170     PISSN: 14727781     EISSN: None     Source Type: Journal    
DOI: 10.1039/p19920002583     Document Type: Article

References (10)

1. For a review: R. A. Hayes and J. C. Martin, Sulfurane Chemistry in Organic Sulfur Chemistry, Theoretical and Experimental Advances, eds. F. Bernardi, I. G. Csizmadia and A. Mangini, Elsevier, Amsterdam, 1985, ch. 8.
2. The Chemistry of Organic Selenium and Tellurium Compounds, vol. 1, eds. S. Patai and Z. Rappoport, Wiley, New York, 1986, ch. 3 and 14. The term tellurane has been used for tetracoordinate tellurium(iv)compounds.
3. The Organic Chemistry of Tellurium, K. J. Irgolic, Gordon and Breach Science Publishers, New York, 1974.
4. SIV-SIV bond: the existence of a SIV-SIV bisulfuranyl dimer, in equilibrium with a sulfuranyl radical, as evidenced by ESR and NMR spectroscopy has been reported.
5. C. W. Perkins and J. C. Martin, J. Am. Chem. Soc., 1986, 108, 321.
6. H. Fujihara, H. Mima, M. Ikemori and N. Furukawa, J. Am. Chem. Soc., 1991, 113,6337.
7. Ch. 6 of ref. 2.
8. P. Girard, J. L. Namy and H. B. Kagan, J. Am. Chem. Soc., 1980,102, 2693
9. J. A. Soderquist, Aldrichimica Acta, 1991, 24, 15.
10. H. Fujihara, T. Ninoi, R. Akaishi, T. Erata and N. Furukawa, Tetrahedron Lett., 1991,32,4537.