Tetraformyltetraselenafulvalene (TFTSeF): Synthesis and some uses as a precursor of polyfunctionalized tetraselenafulvalenes

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 20, 1989, Pages 1520-1521

  Sallé, Marc ^a   Gorgues, Alain ^a   Fabre, Jean Marc ^b   Bechgaard, Klaus ^c   Jubault, Michel ^a   Texier, Fernand ^a  

^a UNIVERSITÉ D'ANGERS   (France)

^b UNIV MONTPELLIER   (France)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049068385     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39890001520     Document Type: Article

References (21)

1. For recent reviews on their syntheses, A. Krief, Tetrahedron, 1986, 42, 1209.
2. M. R. Bryce, Aldrichim. Acta, 1985, 18, 73.
3. F. Bertho-Thoraval, Thesis, Rennes, 4th Oct. 1988, pp. 7-29.
4. TXF (X = P) has also been prepared recently: N. Maigrot, L. Ricard, C. Charrier, and F. Mathey, Angew. Chem., Int. Ed. Engl., 1988, 27, 950.
5. Z. I. Yoshida and T. Sugimoto, Angew. Chem., Int. Ed. Engl., 1988, 27, 1573.
6. For recent results, see Proceedings of the International Conference on Science and Technology of Synthetic Metals (ICSM 88), Santa Fe, June 26-July 2 1988, in Synth. Met., 1988, 27, Bl-B576.
7. H. Inokuchi, Angew. Chem., Int. Ed. Engl., 1988, 27, 1747.
8. S. Rajeswari, Y. A. Jackson, and M. P. Cava, J. Chem. Soc., Chem. Commun., 1988, 1089.
9. A. Gorgues, P. Batail, and A. Le Coq, J. Chem. Soc., Chem. Commun., 1983, 405.
10. A. Gorgues, Janssen Chim. Acta, 1986, 4, 21.
11. A. Gorgues, A. Simon, A. Le Coq, A. Hercouet, and F. Corre, Tetrahedron, 1986, 42, 351.
12. D. Stephan, A. Gorgues, A. Belyasmine, and A. Le Coq, J. Chem. Soc., Chem. Commun., 1988, 263.
13. This reaction proceeds faster with the ethylene triseleno- than with the trithio-carbonate, as when dimethyl acetylenedicarboxylate is used as the electrophilic alkyne M. V. Lakshmikantham and M. P. Cava, J. Org. Chem., 1976, 41, 882.
14. L. Henrisksen, Acta Chem. Scand., 1967, 21, 1981.
15. G. Le Coustumer and Y. Mollier, J. Chem. Soc., Chem. Commun., 1980, 38.
16. As previously noticed in other experiments, we have observed the formation of transient organometallic species which thermally evolve into (4).
17. A. Gorgues, P. Batail, and A. Le Coq, J. Chem. Soc., Chem. Commun., 1983, 405.
18. H. Alper and H. N. Paik, J. Org. Chem., 1977, 42, 3522.
19. Stereochemistry assigned by analogy with the X-ray structures of the sulphur analogues, A. Gorgues and P. Batail, unpublished results.
20. C. U. Pittman, M. Narita, and Y. F. Liang, J. Org. Chem., 1976, 41, 2865.
21. S. Y. Hsu and L. Y. Chiang, Synth. Met., 1988, 27, B651.