Reaction of a stable N ∴ N bonded radical cation with free radicals generated by pulse radiolysis: Exceedingly rapid hydrogen abstraction from C-H bonds

Journal of the Chemical Society, Perkin Transactions 2

Volumn , Issue 2, 1986, Pages 277-284

  Alder, Roger W ^a   Bonifačić, Marija ^b   Asmus, Klaus Dieter ^b  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b HAHN MEITNER INSTITUT   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049068184     PISSN: 1472779X     EISSN: None     Source Type: Journal    
DOI: 10.1039/P29860000277     Document Type: Article

References (35)

1. R. W. Alder, R. B. Sessions, J. M. Mellor, and M. F. Rawlins, J. Chem. Soc., Chem. Commun., 1977, 747.
2. R. W. Alder and R. B. Sessions, J. Am. Chem. Soc., 1979, 101, 3651.
3. R. W. Alder, Acc. Chem. Res., 1983, 16, 321.
4. R. W. Alder and R. B. Sessions, unpublished results.
5. R. W. Alder, R. J. Arrowsmith, A. Casson, R. B. Sessions, E. Heilbronner, B. Kovac, H. Huber, and M. Taagepera, J. Am. Chem. Soc., 1981, 103, 6137.
6. K.-D. Asmus, Acc. Chem. Res., 1979, 12, 436.
7. K.-D. Asmus, D. Bahnemann, Ch.-H. Fischer, and D. Veitwisch, J. Am. Chem. Soc., 1979, 101, 5322.
8. M. Göbl, M. Bonifacic, and K.-D. Asmus, J. Am. Chem. Soc., 1984, 106, 5984.
9. S. F. Nelsen, R. W. Aider, R. B. Sessions, K.-D. Asmus, K.-O. Hiller, and M. Gobl, J. Am. Chem. Soc., 1980, 102, 1429.
10. R. W. Alder, A. G. Orpen, and J. M. White, J. Chem. Soc., Chem. Commun., 1985, 949.
11. R. W. Aider, R. B. Sessions, A. J. Bennet, and R. E. Moss, J. Chem. Soc., Perkin Trans. 1, 1982, 603.
12. K.-D. Asmus, ‘Methods in Enzymology,’ ed. L. Packer, Academic, New York, 1984, vol. 105, pp. 167-178.
13. K.-D. Asmus and E. Janata, in ‘The Study of Fast Processes and Transient Species by Electron Pulse Radiolysis,’ eds. J. H. Baxendale and F. Busi, Reidel, Dordrecht, 1982, pp. 91-113.
14. H. A. Schwarz and R. W. Dodson, J. Phys. Chem., 1984, 88, 3643.
15. R. W. Aider, R. B. Sessions, J. O. Gmünder, and C. A. Grob, J. Chem. Soc., Perkin Trans. 2, 1984, 411.
16. in this reaction the iminium ion (IV) can be trapped with CN- ions.
17. F. O. Rice and E. Teller, J. Chem. Phys., 1938, 6, 489.
18. J. A. Altmann, O. S. Tee, and K. Yates, J. Am. Chem. Soc., 1976, 98, 7132.
19. J. Hine, Adv. Phys. Org. Chem., 1977, 15, 1.
20. R. W. Alder, A. G. Orpen, and R. B. Sessions, J. Chem. Soc., Chem. Commun., 1983, 999.
21. L. Brammer and A. G. Orpen, unpublished results.
22. R. W. Alder, R. J. Arrowsmith, C. St. J. Boothby, E. Heilbronner, and Yang Zhong-Zhi, J. Chem. Soc., Chem. Commun., 1982, 940.
23. B. Kirste, R. W. Alder, R. B. Sessions, M. Bock, H. Kurreck, and S. F. Nelsen, J. Am. Chem. Soc., 1985, 107, 2635.
24. A. Henglein, Radiat. Phys. Chem., 1980, 15, 151.
25. A. T. Thornton and G. S. Lawrence, J. Chem. Soc., Dalton Trans., 1973, 804, 1632, 1637.
26. G. Nord, B. Pederson, E. Floryan-Løvberg, and P. Pagsberg, Inorg. Chem., 1982, 21, 2327.
27. R. W. Alder, R. E. Moss, and R. B. Sessions, J. Chem. Soc., Chem. Commun., 1983, 997.
28. K.-D. Asmus, H. J. Mockel, and A. Henglein, J. Phys. Chem., 1973, 77, 1218.
29. J. Lilie, G. Beck, and A. Henglein, Ber. Bunsenges. Phys. Chem., 1971, 75, 458.
30. A. J. Swallow in ‘Radiation Chemistry,’ Longman, London, 1973.
31. W. T. Dixon, R. O. C. Norman, and A. J. Buley, J. Chem. Soc., 1964, 3625.
32. R. O. C. Norman and B. C. Gilbert, Adv. Phys. Org. Chem., 1967, 5, 53.
33. D. Veltwisch, E. Janata, and K.-D. Asmus, J. Chem. Soc., Perkin Trans. 2, 1980, 146.
34. ‘Landolt-Bornstein. Numerical Data and Functional Relationships in Science and Technology,’ New Series, Group II, ‘Radical Reaction Rates in Liquids,’ ed. H. Fischer, vol. 13b, Springer Verlag, Berlin, 1984.
35. K. Schafer and K.-D. Asmus, J. Phys. Chem., 1981, 85, 852.