Enantioselectivity in organo transition metal chemistry. An unprecedented ligand effect in π-allyl palladium chemistry

Journal of the Chemical Society, Chemical Communications

Volumn , Issue 11, 1988, Pages 718-719

  Genet J P ^a   Juge S ^a   Montès, J Ruiz ^a   Gaudin, J M ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 37049067242     PISSN: 00224936     EISSN: None     Source Type: Journal    
DOI: 10.1039/C39880000718     Document Type: Article

References (18)

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16. After acidic hydrolysis allylglycine methyl ester was obtained: U. Schollkopf, W. Hartwig, K. H. Pospischil, and H. Kehne, Synthesis, 1981, 967.
17. For a mechanistic discussion of the asymmetric catalytic Pd allylation, see: P. B. Mackenzie, J. Whelan, andB. Bosnich, J. Am. Chem. Soc, 1985, 107, 2046.
18. A reversed enantioselection has been also observed in titanium mediated formation of C-O bonds: M. G. Finn and K. B. Sharpless, 'Asymmetric Synthesis,' ed. J. D. Morisson, Academic Press, 1985, vol. 5, p. 290.