Accurate dissociation energies from rotational predissociation and long-range forces: B1II LiH

The Journal of Chemical Physics

Volumn 59, Issue 10, 1973, Pages 5298-5303

  Way, Kermit R ^a   Stwalley, William C ^a  

^a UNIVERSITY OF IOWA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 36849109933     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1679873     Document Type: Article

References (45)

1. A Critical Examination of the Relation of Long-Range Forces to the Interpretation of Diatomic Spectra near Dissociation
2. Energy Levels of a Diatomic Near Dissociation: Dependence on the Determination of the Long-Range Potential
3. also available as University of Wisconsin.
4. See, for example
5. Here we ignore the various small contributions to the potential of the order of m e/μ which make the potential for LiH very slightly different than that for LiD; see Ref. 30.
6. The Utility of Mass-Reduced Quantum Numbers
7. We wish to thank Professor K. Kaiser for making his “tensioned spline” program available to us.
8. See, e.g., the analogous case of OH in Ref. 14.
9. Even though this perturbation seems relatively weak [i.e., the Λ doubling [formula omitted] in [formula omitted] is barely observable], the consequences could be particularly significant in [formula omitted] of LiD (thus far unobserved) since this very weakly bound level could have rotational predissociation occuring at different [formula omitted] in [formula omitted] than in [formula omitted]
10. Diatomic Predissociation Line Widths
11. The authors wish to thank Professor K. Sando for making available his eigenvalue and bound-to-free intensity program. See
12. The ground state potential is from