An EPR study of Cr3+:K2SbF5

Journal of Chemical Physics

Volumn 58, Issue 4, 1973, Pages 1487-1495

  Hempel, J C ^a   Klassen, D ^a   Hatfield, W E ^a   Dearman, H H ^a  

^a UNIVERSITY OF NORTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 36849100053     PISSN: 00219606     EISSN: 10897690     Source Type: Journal    
DOI: 10.1063/1.1679384     Document Type: Article

References (41)

1. T. P. P. Hall, W. Hayes, R. W. H. Stevenson, and J. Wilkens, J. Chem. Phys. 38, 1977 (1963).
2. L. Helmholtz, A. V. Guzzo, and R. N. Sanders, J. Chem. Phys. 35, 1349 (1961).
3. V. V. Grecu and B. M. Wanklyn, J. Phys. C 1968, 387.
4. M. Tinkham, Proc. Roy. Soc. (London) A236, 535 (1956).
5. M. Peter and J. B. Mock, Phys. Rev. 118, 137 (1960).
6. M. M. Zaripov, V. S. Kropotov, L. D. Livanova, and V. G. Stepanov, Sov. Phys. Solid State 9, 155 (1967).
7. M. M. Zaripov, V. S. Kropotov, L. D. Livanova, A. L. Stolov, and Z. S. Yakovleva, Fiz. Tverd. Tela 8, 3680 (1966).
8. A. Byström and K. A. Wilhelmi, Arkiv Kemi 3, 461 (1951).
9. T. Birchall, B. DellaValle, Can. J. Chem. 49, 2808 (1971).
10. J. M. Flowers, J. C. Hempel, W. E. Hatfield, and H. H. Dearman, J. Chem. Phys. 58, 1479 (1973), preceding article.
11. E. L. Muetterties and R. A. Schunn, Quart. Rev. (London) 20, 245 (1966).
12. C. Furlani, Coordin. Chem. Rev. 3, 141 (1968).
13. (c) J. A. Ibers, Ann. Rev. Phys. Chem. 16, 380 (1965).
14. R. M. Macfarlane, J. Chem. Phys. 40, 373 (1964).
15. H. M. Gladney and J. D. Swalen, J. Chem. Phys. 42, 1999 (1965).
16. J. P. Jesson, J. Chem. Phys. 48, 161 (1968).
17. L. F. Hamilton and S. G. Simpson, Quantitative Chemical Analysis (McGraw-Hill, New York, 1947), Chap 14.
18. J. S. Griffiths, Theory of Transition Metal Ions (Cambridge U.P., Cambridge, England) 1961.
19. C. J. Ballhausen, Introduction to Ligand Field Theory (McGraw-Hill, New York) 1962.
20. R. M. Macfarlane, J. Chem. Phys. 39, 3118 (1963).
21. G. Racah, Phys. Rev. 62, 438 (1942).
22. C. W. Nielson and G. F. Kaster, Spectroscopic Coefficients for the [formula omitted] [formula omitted] and [formula omitted] Configurations (Tech. Press, Cambridge, Mass.) 1963.
23. T. M. Dunn and W. K. Li, J. Chem. Phys. 46, 2907 (1967).
24. M. Rotenberg, R. Bivins, N. Metropolis, and J. K. Wooten, Jr., The 3-j and 6-j Symbols (Tech. Press, Cambridge, Mass.) 1959.
25. H. Statz and G. F. Koster, Phys. Rev. 115, 1568 (1959).
26. A. Abragam and B. Bleaney, Electron Paramagnetic Resonance of Transition Ions (Clarendon, Oxford, England) 1970.
27. Internuclear distances not specifically given in Ref. 7 were calculated using the crystal symmetry and structure constants reported in Ref. 7 (computer program SADIAN, written by W. H. Baur).
28. B. Bleaney and K. W. H. Stevens, Rept. Progr. Phys. 16, 108 (1953).
29. B. R. McGarvey, “Electron Spin Resonance of Transition Metal Complexes,” in Transition Metal Chemistry (Dekker, New York, 1966), Vol 3.
30. H. Goldstein, Classical Mechanics (Addison-Wesley, Reading, Mass., 1950), pp. 107–109.
31. EPR parameters were fitted using computer programs written by H. M. Gladney, QCPE 68 and 69.
32. L. L. VanReijen, Thesis, Technische Hogeschool, Eindhoven, the Netherlands, 1964.
33. Resonance positions for the site whose symmetry axes correspond to the rotation axes were calculated using a program written by H. M. Gladney, QCPE 68. Others were calculated with a computer program written by J. C. Hempel.
34. C. P. Slichter, Principles of Magnetic Resonance (Harper and Row, New York) 1963.
35. D. B. Chesnut and W. D. Phillips, J. Chem. Phys. 35, 1002 (1961).
36. For a discussion of pentacoordination symmetry see Ref. 11.
37. H. L. Schläfer, H. Gausmann, and H. U. Zander, Inorg. Chem. 6, 1528 (1967).
38. A. B. P. Lever and B. R. Hollebone, J. Am. Chem. Soc. 94, 1816 (1972), and references therein.
39. J. Owen and J. H. M. Thornley, Rept. Progr. Phys. 29, 675 (1966).
40. M. Edstrand, M. Inge, and N. Ingri, Acta Chem. Scand.9, 122 (1955).
41. This convention is the same as that established by P. Kottis and R. Lefebvre, J. Chem. Phys. 39, 393 (1963).