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Volumn 75, Issue 5, 1981, Pages 2205-2214

Theoretical model for enhanced photochemistry on rough surfaces

Author keywords

[No Author keywords available]

Indexed keywords


EID: 36749106655     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.442333     Document Type: Article
Times cited : (259)

References (48)
  • 5
    • 36749105317 scopus 로고
    • For experimental indication of the relation between SERS and the modified local electromagnetic field see (a)
    • (1978) J. Chem. Phys , vol.69 , pp. 4159
    • Moskovitz, M.1
  • 25
    • 85034693429 scopus 로고
    • Proceedings of the VIIth International Conference on Raman Spectroscopy (Ottawa).
    • (1980)
    • Burstein, E.1    Chen, C.Y.2
  • 32
    • 84951187309 scopus 로고    scopus 로고
    • Regions of diminished field exist as well as regions of enhanced field.
  • 45
    • 84951129329 scopus 로고    scopus 로고
    • The harmonic molecule model described in Sec. III and in Table I has been used. This is of course an oversimplified picture of multiphoton excitation. A more general anharmonic model with a realistic dependence of μ on the intramolecular coordinate can be used, utilizing the formalism of Ref. 17.
  • 46
    • 85034697348 scopus 로고    scopus 로고
    • 2a, 2b For example, for a molecule lying along the long axis of a spheroid [characterized by long and short axes and, respectively, with [formula omitted] and [formula omitted] such that μ is perpendicular to the spheroid surface, the molecule is coupled to the dipolar plasmon directed along the long axis. For this plasmon we get [formula omitted] where [formula omitted] and where [formula omitted] satisfies [formula omitted] [A. Nitzan (unpublished result)]. The corresponding Γ may be calculated using the procedure of Ref. 18.


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