The oxidation of iron(II) with oxygen in NaCl brines

Journal of Solution Chemistry

Volumn 36, Issue 11-12, 2007, Pages 1479-1493

  Trapp, J Michael ^a   Millero, Frank J ^a  

^a UNIVERSITY OF MIAMI   (United States)

Author keywords

Brines; Fe(II); NaCl; Oxidation

Indexed keywords

EID: 36749096323     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10953-007-9192-8     Document Type: Article

References (26)

1. Stumm, W., Lee, G.F.: Oxygenation of ferrous iron. Ind. Eng. Chem. 53, 143-146 (1961)
2. Lowson, R.T.: Aqueous oxidation of pyrite by molecular oxygen. Chem. Rev. 82, 461-499 (1982)
3. Sung, W., Morgan, J.J.: Kinetics and product of ferrous oxygenation in aqueous solutions. Environ. Sci. Technol. 14, 561-568 (1980)
4. Millero, F.J.: The effect of ionic interactions on the oxidation of metals in natural waters. Geochim. Cosmochim. Acta 49, 547-553 (1985)
5. Roekens, E.J., Van Grieken, R.E.: Kinetics of iron (II) oxidation in seawater of various pH. Mar. Chem. 13, 195-202 (1983)
6. Wilkins, R.G.: The Study of Kinetics and Mechanism of Reactions of Transition Metal Complexes, p. 403. Allyn and Bacon, Boston (1974)
7. Baes, C.F., Mesmer, R.E.: Iron. In: Baes, C.F., Mesmer, R.E. (eds.) The Hydrolysis of Cations, p. 489. Wiley, New York (1976)
8. Millero, F.J., Izaguirre, M.: Effect of ionic strength and ionic interactions on the oxidation of Fe(II). J. Solution Chem. 18, 585-599 (1989)
9. Millero, F.J., Izaguirre, M., Sharma, V.K.: The effect of ionic interactions on the rates of oxidation in natural waters. Mar. Chem. 22, 179-191 (1990)
10. 2 in seawater. Geochim. Cosmochim. Acta 53, 1867-1873 (1989)
11. Millero, F.J., Sotolongo, S., Izaguirre, M.: The kinetics of oxidation of Fe(II) in seawater. Geochim. Cosmochim. Acta 51, 793-801 (1987)
12. 2. J. Solution Chem. 20, 1079-1092 (1991)
13. Ghosh, M.M.: Oxygenation of ferrous iron(II) in highly buffered water. In: Rubin, A.J. (ed.) Aqueous Environment of Metals, pp. 193-217. Ann Arbor Science, Ann Arbor (1974)
14. King, D.W.: Role of carbonate speciation on the oxidation rate of Fe(II) in aquatic systems. Environ. Sci. Technol. 32, 2997-3003 (1998)
15. King, D.W., Lounsbury, H.A., Millero, F.J.: Rates and mechanism of Fe(II) oxidation at nanomolar total iron concentrations. Environ. Sci. Technol. 29, 818-824 (1995)
16. Santana-Casiano, J.M., Gonzalez-Davila, M., Rodriquez, M.J., Millero, F.J.: The effects of organic compounds in the oxidation kinetics of Fe(II). Mar. Chem. 70, 211-222 (2000)
17. - and seawater solutions in the presence of phthalate and salicylate ions: a kinetic model. Mar. Chem. 85, 27-40 (2004)
18. Santana-Casiano, J.M., Gonzalez-Davila, M., Rodriquez, M.J., Millero, F.J.: Oxidation of nanomolar levels of iron(II) with oxygen in seawater. Environ. Sci. Technol. 39, 2073-2079 (2005)
19. 2 in the oxidation of Fe(II) in natural waters. J. Solution Chem. 35, 95-111 (2006)
20. Harber, F., Weiss, J.: The catalytic decomposition of hydrogen peroxide by iron salts. Proc. R. Soc. London (Ser. A) 149, 332-351 (1934)
21. Zhang, J.Z., Kelble, C., Millero, F.J.: Gas-segmented continuous flow analysis of iron in water with a long liquid waveguide capillary flow cell. Anal. Chim. Acta 438, 49-57 (2001)
22. -1 to saturation and from 273.15 to 323.15 K. J. Chem. Thermodyn. 13, 649-662 (1982)
23. Millero, F.J., Yao, W., Aicher, J.: The speciation of Fe(II) and Fe(III) in seawater. Mar. Chem. 50, 21-39 (1995)
24. Millero, F.J., Pierrot, D.: A chemical equilibrium model for natural waters. Aqua Geochem. 4, 153-199 (1998)
25. Millero, F.J., Huang, F., Laferriere, A.L.: Solubility of oxygen in the major sea salts as a function of temperature and concentration. Mar. Chem. 78, 217-230 (2002)
26. th Annual V.M. Goldschmidt Conference, Copenhagen, Denmark, June 5-11, 2004