Complexes of technetium(I) (99Tc, 99mTc) pentacarbonyl core with π-acceptor ligands (tert-butyl isocyanide and triphenylphosphine): Crystal structures of [Tc(CO)5(PPh3)]OTf and [Tc(CO)5(CNC(CH3)3)]ClO4

Journal of Organometallic Chemistry

Volumn 693, Issue 1, 2008, Pages 4-10

  Miroslavov, A E ^a   Lumpov, A A ^a   Sidorenko, G V ^a   Levitskaya, E M ^a   Gorshkov, N I ^a   Suglobov, D N ^a   Alberto, R ^b   Braband, H ^b   Gurzhiy, V V ^c   Krivovichev, S V ^c   Tananaev, I G ^d  

^a KHLOPIN RADIUM INSTITUTE   (Russian Federation)

^b UNIVERSITY OF ZURICH   (Switzerland)

^c ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^d FRUMKIN INSTITUTE OF PHYSICAL CHEMISTRY AND ELECTROCHEMISTRY   (Russian Federation)

Author keywords

Carbonyls; Technetium; tert Butyl isocyanide; Triphenylphosphine

Indexed keywords

CARBONYLATION; CRYSTAL STRUCTURE; LIGANDS; SYNTHESIS (CHEMICAL); TECHNETIUM;

CARBONYLS; PENTACARBONYL CORE; TERT-BUTYL ISOCYANIDE; TRIPHENYLPHOSPHINE;

METAL COMPLEXES;

EID: 36749077017     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.09.032     Document Type: Article

References (28)

1. Alberto R., Schibli R., Waibel R., Abram U., and Schubiger A.P. Coord. Chem. Rev. 190-192 (1999) 901
2. Technetium, Rhenium and Other Metals in Chemistry and Nuclear Medicine, SGEditorial, Padova, 2006.
3. Alberto R., Ortner K., Wheatley N., Schibli R., and Schubiger A.P. J. Am. Chem. Soc. 123 (2001) 3135
4. Miroslavov A.E., Sidorenko G.V., Borisova I.V., et al. Radiokhimiya 32 6 (1990) 14
5. Borisova I.V., Miroslavov A.E., Sidorenko G.V., and Suglobov D.N. Radiokhimiya 33 3 (1991) 1
6. Borisova I.V., Miroslavov A.E., Sidorenko G.V., and Suglobov D.N. Radiokhimiya 33 6 (1991) 1
7. Borisova I.V., Miroslavov A.E., Sidorenko G.V., et al. Radiokhimiya 33 4 (1991) 27
8. Atwood J.D., and Brown T.L. J. Am. Chem. Soc. 98 (1976) 3160
9. Borisova I.V., Miroslavov A.E., Sidorenko G.V., and Suglobov D.N. Radiokhimiya 33 6 (1991) 9
10. SU Inventor's Certificate 1512003.
11. Akopov G.A., Krinitsyn A.P., and Tsarenko A.F. Radiokhimiya 29 3 (1987) 589
12. RF patent 2294897.
13. stoe-ipds Software package, STOE & Cie, GmbH: Darmstadt, Germany, 1999.
14. Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., Guagliardi A., Moliterni A.G.G., Polidori G., and Spagna R. J. Appl. Crystallogr. 32 (1999) 15
15. Farrugia L.J. J. Appl. Crystallogr. 30 (1997) 565
16. Sheldrick G.M. SHELXL97-2: Program for the Refinement of Crystal Structures (1997), University of Göttingen, Germany
17. RF Patent 2125017.
18. Aebischer N., Schibli R., Alberto R., and Merbach A.E. Angew. Chem., Int. Ed. 39 (2000) 254
19. Gorshkov N.I., Lumpov A.A., Miroslavov A.E., Mikhalev V.A., et al. Czech. J. Phys. Suppl. A 53 (2003) A745
20. Gorshkov N.I., Schibli R., Schubiger A.P., Lumpov A.A., et al. J. Organomet. Chem. 689 (2004) 4757
21. Steil P., Nagel U., and Beck W. J. Organomet. Chem. 339 (1988) 111
22. R. Schibli, PhD Thesis, Basel, 1996.
23. Miroslavov A.E., Sidorenko G.V., Borisova I.V., et al. Radiokhimiya 32 4 (1990) 6
24. Abram U., Beyer R., Muenze R., et al. Polyhedron 8 (1989) 1201
25. Steil P., Nagel U., and Beck W. J. Organomet. Chem. 366 (1989) 313
26. Bailey M.F., and Dahl L.F. Inorg. Chem 4 (1965) 1140
27. Grigor'ev M.S., Miroslavov A.E., Sidorenko G.V., and Suglobov D.N. Radiokhimiya 39 3 (1997) 204
28. Hileman J.C., Huggins D.K., and Kaesz H.D. Inorg. Chem. 1 (1962) 933