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37049111808
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Catalytic effect of halides in cross-coupling reactions was first reported by T. Jeffery (Jeffery, T. J. Chem. Soc., Chem. Commun. 1984, 1287-1288). See also ref 38 for the use of halides in other cross-couplings and Heck reactions.
-
Catalytic effect of halides in cross-coupling reactions was first reported by T. Jeffery (Jeffery, T. J. Chem. Soc., Chem. Commun. 1984, 1287-1288). See also ref 38 for the use of halides in other cross-couplings and Heck reactions.
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36
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0000852316
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41
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36749102478
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3N in the presence of an aryl halide.
-
3N in the presence of an aryl halide.
-
-
-
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42
-
-
36749052768
-
-
3 was observed.
-
3 was observed.
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-
-
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43
-
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36749097786
-
-
Structures for an intermediate resonating at δp, 95.5 shown in Scheme 3 and the related intermediates in Scheme 5 are only tentative. These, and other low ligated intermediates discussed in this paper are, most likely stabilized via coordination of solvent molecules (that are omitted from the structures) and may have geometries different from those shown in the schemes
-
Structures for an intermediate resonating at δp = 95.5 shown in Scheme 3 and the related intermediates in Scheme 5 are only tentative. These, and other low ligated intermediates discussed in this paper are, most likely stabilized via coordination of solvent molecules (that are omitted from the structures) and may have geometries different from those shown in the schemes.
-
-
-
-
44
-
-
36749096166
-
-
- species apparently cannot be formed during the reductive elimination step of the catalytic cycle; otherwise, the H-phosphonate present would intercept it and arrest the catalytic reaction.
-
- species apparently cannot be formed during the reductive elimination step of the catalytic cycle; otherwise, the H-phosphonate present would intercept it and arrest the catalytic reaction.
-
-
-
-
48
-
-
36749074366
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-
To be specific, a complex formed first in the oxidative addition is assumed to be a trigonal bipyramid PhPdII(PPh3) 2G1X that, in the presence of a minute amount of free PPh3 (which is the case for Pd(PPh3)4 or Pd(OAc)2, 3PPh3, quickly collapses to trans-PhPdII(PPh3)2G2 with the expulsion of G1 or X. For details, see refs 24 (review, 40 (G1, OAc, and 41 G1, Cl
-
1 = Cl).
-
-
-
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49
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0001589134
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Amatore, C.; Carré, E.; Jutand, A.; M'Barki, M. A.; Meyer, G. Organometallics 1995, 14, 5605-5614.
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50
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0001606053
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Amatore, C.; Jutand, A.; Suarez, A. J. Am. Chem. Soc. 1993, 115, 9531-9541.
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Amatore, C.1
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51
-
-
36749083335
-
-
-, and large differences in equilibria constants enable a practically quantitative replacement of the anion lower in the row with the one which is higher. See also refs 24 and 40.
-
-, and large differences in equilibria constants enable a practically quantitative replacement of the anion lower in the row with the one which is higher. See also refs 24 and 40.
-
-
-
-
52
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36749058837
-
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2I in the reaction with styrene (syn-insertion step of the Heck reaction). See also ref 41.
-
2I in the reaction with styrene (syn-insertion step of the Heck reaction). See also ref 41.
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