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Volumn 111, Issue 45, 2007, Pages 11524-11530

Electrolyte-concentration and ion-size dependence of excited-state intramolecular charge-transfer reaction in (alkylamino)benzonitriles: Time-resolved fluorescence emission studies

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; CONCENTRATION (PROCESS); FLUORESCENCE; IONS; MOLECULAR STRUCTURE; SOLVENTS;

EID: 36749061969     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp075825a     Document Type: Article
Times cited : (38)

References (33)
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    • J. Phys. Chem
    • J. Phys. Chem. 1982, 86, 1970.
    • (1970) , vol.86
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    • Chem. Phys. Lett. 1997, 268, 110.
    • (1997) Phys. Lett , vol.268 , pp. 110
    • Chem1
  • 28
    • 36749058708 scopus 로고    scopus 로고
    • 2 = 0.99.
    • 2 = 0.99.
  • 30
    • 36749034564 scopus 로고    scopus 로고
    • 2 ∼ 1.0 for all cases. It is interesting to note that similar biexponential fitting has also been obtained for several steady-state properties studied in ref 1.
    • 2 ∼ 1.0 for all cases. It is interesting to note that similar biexponential fitting has also been obtained for several steady-state properties studied in ref 1.
  • 31
    • 36749099766 scopus 로고    scopus 로고
    • If we use a, 0.47 for P4C as mentioned in ref 14, the calculated rate deviates strongly from the observed rate at all electrolyte concentrations considered here. However, a, 0.1 produces a reasonable agreement with the observed rate for P4C at all LiClO4 concentrations in ethyl acetate, as shown in the upper panel of Figure 4. For P5C and P6C, values of a used in the calculation are 0.42 and 0.45, respectively see ref 14
    • 4 concentrations in ethyl acetate, as shown in the upper panel of Figure 4. For P5C and P6C, values of a used in the calculation are 0.42 and 0.45, respectively (see ref 14).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.