The 2,4,6-trimethoxyphenyl unit as a unique protecting group for silicon in synthesis and the silylation potential of (2,4,6-trimethoxyphenyl)silanes

Organometallics

Volumn 26, Issue 24, 2007, Pages 6014-6028

  Popp, Friedrich ^a   Nätscher, Jennifer B ^a   Daiss, Jürgen O ^a   Burschka, Christian ^a   Tacke, Reinhold ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; BYPRODUCTS; CHARACTERIZATION; DERIVATIVES; FUNCTIONAL GROUPS; NUCLEOPHILES; REGIOSELECTIVITY; SILANES; SYNTHESIS (CHEMICAL);

CHLORIDE SOLUTIONS; SILYLATION; TRIMETHOXYPHENYL UNITS;

SILICON;

EID: 36749024436     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700805p     Document Type: Article

References (30)

1. Daiss, J. O.; Penka, M.; Burschka, C.; Tacke, R. Organometallics 2004, 23, 4987-4994.
2. (a) Benkeser, R. A.; Krysiak, H. R. J. Am. Chem. Soc. 1953, 75, 4528-4531.
3. (b) Eaborn, C. J. Chem. Soc. 1953, 3148-3153.
4. (c) Eaborn, C. J. Organomet. Chem. 1975, 100, 43-57.
5. (d) Bennetau, B.; Rajarison, F.; Dunoguès, J.; Babin, P. Tetrahedron 1993, 49, 10843-10854.
6. (e) Radner, F.; Wistrand, L.-G. Tetrahedron Lett. 1995, 36, 5093-5094.
7. (f) Utimoto, K.; Otake, Y.; Yoshino, H.; Kuwahara, E.; Oshima, K.; Matsubara, S. Bull. Chem. Soc. Jpn. 2001, 74, 753-754.
8. (g) Anderson, T. F.; Statham, M. A. ].; Carroll, M. A. Tetrahedron Lett. 2006, 47, 3353-3355.
9. (a) Bott, R. W.; Eaborn, C.; Jackson, P. M. J. Organomet. Chem. 1967, 7, 79-83.
10. (b) Eaborn, C.; Salih, Z. S.; Walton, D. R. M. J. Organomet. Chem. 1972, 36, 47-48.
11. (a) Bassindale, A. R.; Stout, T. J. Organomet. Chem. 1984, 271, C1C3.
12. (b) Coppi, L.; Ricci, A.; Taddei, M. Tetrahedron Lett. 1987, 28, 965968.
13. (c) Uhlig, W.; Tzschach, A. J. Organomet. Chem. 1989, 378, C1C5.
14. (d) Uhlig, W. J. Organomet. Chem. 1991, 402, C45-C49.
15. (e) Uhlig, W. J. Organomet. Chem. 1993, 452, 29-32.
16. (f) Uhlig, W. Chem. Ber. 1996, 129, 733-739.
17. (g) Goetze, B.; Herrschaft, B.; Auner, N. Chem. Eur. J. 1997, 3, 948-957.
18. (h) wa Mutahi, M.; Nittoli, T.; Guo, L.; Sieburth, S. McN. J. Am. Chem. Soc. 2002, 124, 7363-7375.
19. (a) Häbich, D.; Effenberger, F. Synthesis 1978, 755-756.
20. (b) Eaborn, C.; Lickiss, P. D.; Ramadan, N. A. J. Chem. Soc. Perkin Trans II 1984, 267-270.
21. (c) Schwager, H.; Spyroudis, S.; Vollhardt, K. P. C. J. Organomet. Chem. 1990, 382, 191-200.
22. (d) Eaborn, C.; Jones, K. L.; Lickiss, P. D. J. Organomet. Chem. 1993, 461, 31-34.
23. (a) Kocienski, P. J. Protecting Groups, Georg Thieme Verlag, Stuttgart, 2000; pp 28-42.
24. (b) Greene, T. W.; Wuts, P. G. M. Protective Groups in Organic Synthesis, 3rd ed.; John Wiley & Sons, Inc.: New York, 1999; pp 113-148.
25. Hatanaka, Y.; Goda, K.-i.; Okahara, Y.; Hiyama, T. Tetrahedron 1994, 50, 8301-8316.
26. (a) Crowther, G. P.; Sundberg, R. J.; Sarpeshkar, A. M. J. Org. Chem. 1984, 49, 4657-4663.
27. (b) Cabiddu, S.; Contini, L.; Fattuoni, C.; Floris, C.; Gelli, G. Tetrahedron 1991, 47, 9279-9288.
28. (a) Sheldrick, G. M. SHELXS-97; University of Göttingen: Göttingen Germany, 1997.
29. (b) Sheldrick, G. M. Acta Crystallor. Sect. A 1990, 46, 467-473.
30. Sheldrick, G. M. SHELXS-97; University of Göttingen: Göttingen Germany, 1997.