Comparison of molecularly imprinted solid-phase extraction (MISPE) with classical solid-phase extraction (SPE) for the detection of benzodiazepines in post-mortem hair samples

Forensic Science International

Volumn 174, Issue 1, 2008, Pages 40-46

  Anderson, Robert A ^a   Ariffin, Marinah M ^a   Cormack, Peter A G ^b   Miller, Eleanor I ^a  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

^b University of Strathclyde   (United Kingdom)

Author keywords

Benzodiazepines; Hair; LC MS MS; MISPE; SPE

Indexed keywords

BENZODIAZEPINE; DIAZEPAM; NITRAZEPAM; NORDAZEPAM; OXAZEPAM; TEMAZEPAM;

ARTICLE; AUTOPSY; CONTROLLED STUDY; DRUG DETERMINATION; HAIR ANALYSIS; HUMAN; HUMAN TISSUE; LIQUID CHROMATOGRAPHY; MOLECULAR IMPRINTING; PRIORITY JOURNAL; SOLID PHASE EXTRACTION; TANDEM MASS SPECTROMETRY;

EID: 36749004411     PISSN: 03790738     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.forsciint.2007.03.002     Document Type: Article

References (32)

1. Kronstrand R., Nyström I., Josefsson M., and Hodgins S. Segmental ion spray LC-MS-MS analysis of benzodiazepines in hair of psychiatric patients. J. Anal. Toxicol. 26 (2002) 479-484
2. In: Salamone S.J. (Ed). Benzodiazepines and GHB, Detection and Pharmacology (2001), Humana Press Inc., New Jersey
3. Seymour A., Black M., and Oliver J.S. Drug related deaths in the Strathclyde region of Scotland 1995-1998. Forensic Sci. Int. 122 (2001) 52-59
4. Seymour A., and Oliver J.S. Role of drugs and alcohol in impaired drivers and fatally injured drivers in the Strathclyde police region of Scotland 1995-1998. Forensic Sci. Int. 103 (1999) 89-100
5. www.isdscotland.org/isd/files/final_F05.xls
6. Yegles M., Mersch F., and Wennig R. Detection of benzodiazepines and other psychotropic drugs in human hair by GC/MS. Forensic Sci. Int. 84 (1997) 211-218
7. Progress in hair analysis for illegal drugs. In: Klaus Muller R., and Thieme D. (Eds). Workshop Proceedings of the International Society of Hair Testing. Kreischa, Sport and Buch Strauss, Cologne, Germany, June 18-20 (2000) 22-34
8. Negrusz A., Bowen A.M., Moore C.M., Dowd S.M., and Strong M.J. Deposition of 7-aminoclonazepam and clonazepam in hair following a single dose of Klonopin™. J. Anal. Toxicol. 26 (2002) 471-478
9. Cirimele V., Kintz P., and Mangin P. Detection and quantification of lorazepam in human hair by GC-MS/NCI in a case of traffic accident. Int. J. Legal Med. 108 (1996) 265-267
10. Cirimele V., Kintz P., and Ludes B. Screening for forensically relevant benzodiazepines in human hair by gas chromatography-negative ion chemical ionization-mass spectrometry. J. Chromatogr. B 700 (1997) 119-129
11. Kintz P., Cirimele V., Vayssette F., and Mangin P. Hair analysis for nordiazepam and oxazepam by gas chromatography-negative-ion chemical ionization mass spectrometry. J. Chromatogr. B 677 (1996) 241-244
12. Mahjoub El., and Staub C. Determination of benzodiazepines in human hair by on-line high-performance liquid chromatography using a restricted access extraction column. Forensic Sci. Int. 123 (2001) 17-25
13. Kronstrand R., Nyström I., Strandberg J., and Druid H. Screening for drugs of abuse in hair with ion spray LC-MS-MS. Forensic Sci. Int. 145 (2004) 183-190
14. Villain M., Concheiro M., Cirimele V., and Kintz P. Screening method for benzodiazepines and hypnotics in hair at pg/mg level by liquid chromatography-mass spectrometry/mass spectrometry. J. Chromatogr. B 825 (2005) 72-78
15. Cheze M., Villain M., and Pepin G. Determination of bromazepam, clonazepam and metabolites after a single intake in urine and hair by LC-MS-MS. Application to forensic cases of drug facilitated crimes. Forensic Sci. Int. 145 (2004) 123-130
16. McClean S., O'Kane E., Hillis J., and Smyth W.F. Determination of 1,4-benzodiazepines and their metabolites by capillary electrophoresis and high-performance liquid chromatography using ultraviolet and electrospray ionisation mass spectrometry. J. Chromatogr. A 838 (1999) 273-291
17. Cheze M., Duffort G., Deveaux M., and Pepin G. Hair analysis by liquid chromatography-tandem mass spectrometry in toxicological investigation of drug-facilitated crimes: report of 128 cases over the period June 2003-May 2004 in metropolitan Paris. Forensic Sci. Int. 153 (2005) 3-10
18. Miller E.I., Wylie F.M., and Oliver J.S. Detection of benzodiazepines in hair by ELISA and LC-ESI-MS-MS. J. Anal. Toxicol. 30 7 (2006) 441-448
19. Ariffin M.M., Miller E.I., Cormack P.A.G., and Anderson R.A. Molecularly imprinted polymer solid-phase extraction of diazepam and its metabolites from hair samples. Anal. Chem. 79 1 (2007) 256-262
20. Hart R.B., Rush D.J., and Shea K.J. Discrimination between enantiomers of structurally related molecules: separation of benzodiazepines by molecularly imprinted polymers. J. Am. Chem. Soc. 122 (2000) 460-465
21. Matsui J., and Takeuchi T. A molecularly imprinted polymer rod as nicotine selective affinity media prepared with 2-(trifluoromethyl) acrylic acid. Anal. Commun. 34 (1997) 199-200
22. Wulff G. Enzyme-like catalysis by molecularly imprinted polymers. Chem. Rev. 102 (2002) 1-28
23. Kriz D., and Mosbach K. Competitive amperometric morphine sensor based on an agarose immobilised molecularly imprinted polymer. Anal. Chim. Acta 300 (1995) 71-75
24. F. Chapuis, V. Pichon, M.-C. Hennion, Molecularly imprinted polymers: developments and applications of new selective solid-phase extraction materials, LC.GC, Europe, 2004, pp. 408-417.
25. Masqué N., Marcé R.M., and Borrull F. Molecularly imprinted polymers: new tailor-made materials for selective solid-phase extraction. Trends Anal. Chem. 20 (2001) 477-486
26. Caro E., Masqué N., Marcé R.M., Borrull F., Cormack P.A.G., and Sherrington D.C. Non-covalent and semi-covalent molecularly imprinted polymers for selective on-line solid-phase extraction of 4-nitrophenol from water samples. J. Chromatogr. A 963 (2002) 169-178
27. Cacho C., Turiel E., Martín-Esteban A., Ayala D., and Pérez-Conde C. Semi-covalent imprinted polymer using propazine methacrylate as template molecule for the clean-up of triazines in soil and vegetable samples. J. Chromatogr. A 1114 (2006) 255-262
28. Bengtsson H., Roos U., and Andersson L.I. Molecular imprint based radioassay for direct determination of s-propranolol in human plasma. Anal. Commun. 34 (1997) 233-235
29. Mullet W.M., and Lai E.P.C. Determination of theophylline in serum by molecularly imprinted solid-phase extraction with pulsed elution. Anal. Chem. 70 (1998) 3636-3641
30. Xia Y., McGuffey J.E., Bhattacharyya S., Sellergren B., Yilmaz E., Wang L., and Bernert J.T. Analysis of the tobacco-specific nitrosamine 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol in urine by extraction on a molecularly imprinted polymer column and liquid chromatography/atmospheric pressure ionization tandem mass spectrometry. Anal. Chem. 77 (2005) 7639-7645
31. Vlatakis G., Anderson L.I., Muller R., and Mosbach K. Drug assay using antibody mimics made by molecular imprinting. Nature 361 (1993) 645-647
32. Scott K.S., and Nakahara Y. A study into the rate of incorporation of eight benzodiazepines into rat hair. Forensic Sci. Int. 133 (2003) 47-56