Preferential solvation of ions in mixed solvents. 5. the alkali metal, silver, and thallium(I) cations in aqueous organic solvents according to the inverse Kirkwood-Buff integral (IKBI) approach

Journal of Solution Chemistry

Volumn 36, Issue 11-12, 2007, Pages 1385-1399

  Marcus, Yizhak ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

Aqueous organic solvent mixtures; Kirkwood Buff integrals; Preferential solvation; Univalent cations

Indexed keywords

EID: 36649024555     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10953-007-9196-4     Document Type: Article

References (16)

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2. Kalidas, C., Hefter, G., Marcus, Y.: Gibbs energies of transfer of cations from water to mixed aqueous organic solvents. Chem. Rev. 100, 820-852 (2000)
3. Marcus, Y.: Solvent Mixtures. Dekker, New York (2002), p. 214 and references cited there
4. Newman, K.E.: Interpretation of free energies of transfer and solute partial molar volumes in mixed solvents using Kirkwood-Buff theory. J. Chem. Soc. Faraday Trans. 1 84, 1387-1391 (1988)
5. Hall, D.G.: Definition of the primary medium effect for individual ionic species in solution. J. Chem. Soc. Faraday Trans. 2 68, 25-32 (1972)
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7. 4B assumption of single ion thermodynamics in amphiprotic and dipolar-aprotic solvents: evaluation of physical parameters relevant to theoretical considerations. Z. Phys. Chem. (NF) 113, 129-150 (1978)
8. Marcus, Y.: Preferential solvation in mixed solvents. 13. Mixtures of tetrahydrofuran with organic solvents: Kirkwood-Buff integrals and volume-corrected preferential solvation parameters. J. Solution Chem. 35, 251-277 (2006) and references cited therein
9. Marcus, Y.: The Properties of Solvents. Wiley, Chichester (1998)
10. Marcus, Y.: Ion Properties. Dekker, New York (1997)
11. Millero, F.J.: The molal volumes of electrolytes. Chem. Rev. 71, 147-176 (1971)
12. Marcus, Y., Hefter, G.: Standard partial molar volumes of electrolytes and ions in nonaqueous solvents. Chem. Rev. 104, 3405-3452 (2004)
13. Nikolova, P.V., Duff, S.J.B., Westh, P., Haynes, C.A., Kasahara, Y., Nishikawa, K., Koga, Y.: A thermodynamic study of aqueous acetonitrile: excess chemical potentials, partial molar enthalpies, entropies and volumes, and fluctuations. Can. J. Chem. 78, 1563-1560 (2000)
14. Marcus, Y.: Preferential solvation of silver(I), copper(I), and copper(II) ions in aqueous acetonitrile. J. Chem. Soc. Dalton Trans. 1991, 2265-2268 (1991)
15. Cox, B.G., Parker, A.J., Waghorne, W.E.: Coordination and ionic solvation. J. Phys. Chem. 78, 1731-1740 (1974)
16. Schneider, H., Strehlow, H.: Selective solvation of ions in solvent mixtures, IV. Z. Phys. Chem. (Munich) 49, 44-57 (1966)