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Volumn 80, Issue 10, 1984, Pages 4701-4717

Investigations of the Stokes and anti-Stokes resonance Raman scattering of cytochrome c

Author keywords

[No Author keywords available]

Indexed keywords


EID: 36549097734     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.446535     Document Type: Article
Times cited : (81)

References (39)
  • 33
    • 85034727040 scopus 로고    scopus 로고
    • For example, if we assume a constant photon scattering rate over a finite frequency range [formula omitted] with [formula omitted] we have [formula omitted] in an Einstein approximation vs [formula omitted] for the exact calculation. For [formula omitted] the Einstein average S is essentially equivalent to the exact result as can be seen from the fact that [formula omitted] is the first term in a logarithmic expansion of In [formula omitted] As [formula omitted] increases, however, the exact result increases more rapidly than the average value and we have [formula omitted]
  • 37
    • 85034725686 scopus 로고    scopus 로고
    • This is due to the back donation of electron density from the iron [formula omitted] orbitals into the porphyrin [formula omitted] orbitals.
  • 39
    • 84951344370 scopus 로고    scopus 로고
    • The unobserved low frequency modes involved in the g′ subspace must obviously be included in model calculations of the absorption line shape even though they are not directly observed in the resonance Raman spectrum. Preliminary modelling results suggest that [formula omitted] and [formula omitted] will lead to results that are inconsistent with the absorption line shape. Further modelling studies may help us to assess the upper limits on the coupling strength to be associated with the unobserved low frequency (g′) subspace.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.