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Volumn 86, Issue 3, 1987, Pages 1118-1124

Benzonitrile and its van der Waals complexes studied in a free jet. II. Dynamics in the excited state: The effect of changing the degrees of freedom of partner molecules

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EID: 36549094493     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.452253     Document Type: Article
Times cited : (44)

References (25)
  • 19
    • 85034876265 scopus 로고    scopus 로고
    • Since the frequency of vdW stretching mode is of the order of [formula omitted] the frequency factor in Eq. (2) for the dissociation of the vdW bond would be [formula omitted] However, the frequencies of the vdW bending modes which certainly participate in energy randomization are well below [formula omitted] Therefore, the frequency factor in expression (2) could be still lower than [formula omitted]
  • 25
    • 85034881332 scopus 로고    scopus 로고
    • Doxtader and Topp reported that the excitation of the perylene‐[formula omitted] complex up to [formula omitted] caused complete dissociation of the complex. Since they estimated the dissociation energy of the complex to be [formula omitted] complete dissociation of the complex by such a small excess energy seems to be questionable on the basis of our analysis. The dissociation energy might be well below [formula omitted]


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.