On the possibility of replacement of Pt by Pd in a hydrogen electrode of PEM fuel cells

International Journal of Hydrogen Energy

Volumn 32, Issue 17, 2007, Pages 4438-4442

  Grigoriev, S A ^a   Lyutikova, E K ^a   Martemianov, S ^b   Fateev, V N ^a  

^a KURCHATOV INSTITUTE   (Russian Federation)

^b UNIVERSITÉ DE POITIERS   (France)

Author keywords

Electrocatalyst; Fuel cell; Membrane electrode assembly (MEA); Palladium; Proton exchange membrane (PEM)

Indexed keywords

ELECTROCATALYSTS; NANOSTRUCTURED MATERIALS; PALLADIUM; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); REDUCTION;

HYDROGEN ELECTRODES; MEMBRANE ELECTRODE ASSEMBLY (MEA);

ELECTROCHEMICAL ELECTRODES;

EID: 36549078090     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2007.02.005     Document Type: Article

References (25)

1. Starz K.A., Auer E., Lehmann Th., and Zuber R. Characteristics of platinum-based electrocatalysts for mobile PEMFC applications. J Power Sources 84 (1999) 167-172
2. Xiong L., and Manthiram A. High performance membrane-electrode assemblies with ultra-low Pt loading for proton exchange membrane fuel cells. Electrochim Acta 50 (2005) 3200-3204
3. Caillard A., Brault P., Mathias J., Charles C., Boswell R.W., and Sauvage T. Deposition and diffusion of platinum nanoparticles in porous carbon assisted by plasma sputtering. Surf Coat Technol 200 (2005) 391-394
4. Karyakin A.A., Morozov S.V., Karyakina E.E., Varfolomeyev S.D., Zorin N.A., and Cosnier S. Hydrogen fuel electrode based on bioelectrocatalysis by the enzyme hydrogenase. Electrochem Commun 4 (2002) 417-420
5. Tarasevich M.R., Bogdanovskaya V.A., and Kapustin A.V. Nanocomposite material laccase/dispersed carbon carrier for oxygen electrode. Electrochem Commun 5 (2003) 491-496
6. Tyurin V.S., Bogatyreva G.P., Zhutaeva G.V., Korovin N.V., Marinich M.A., Radyushkina K.A., et al. Pyropolymer-based oxygen electrode for solid polymer electrolyte systems. Russ J Electrochem 37 (2001) 1085-1088
7. Tyurin V.S., Radyushkina K.A., Levina O.A., and Tarasevich M.R. Electrocatalytic properties of a composite based on cobalt porphyrin pyropolymer and Nafion. Russ J Electrochem 37 (2001) 843-847
8. Baranton S., Coutanceau C., Roux C., Hahn F., and Leger J.-M. Oxygen reduction reaction in acid medium at iron phthalocyanine dispersed on high surface area carbon substrate: tolerance to methanol, stability and kinetics. J Electroanal Chem 577 (2005) 223-234
9. Costamagna P., and Srinivasan S. Quantum jumps in the PEMFC science and technology from the 1960s to the year 2000: Part I. Fundamental scientific aspects. J Power Sources 102 (2001) 242-252
10. Ralph T.R., and Hogarth M.P. Catalysis for low temperature fuel cells. Platinum Met Rev 46 (2002) 117-135
11. Dubau L., Hahn F., Coutanceau C., Leger J.M., and Lamy C. On the structure effects of bimetallic PtRu electrocatalysts towards methanol oxidation. J Electroanal Chem 554-555 (2003) 407-415
12. Lamy C., Rousseau S., Belgsir E.M., Coutanceau C., and Leger J.-M. Recent progress in the direct ethanol fuel cell: development of new platinum-tin electrocatalysts. Electrochim Acta 49 (2004) 3901-3908
13. Guo D.-J., and Li H.-L. High dispersion and electrocatalytic properties of palladium nanoparticles on single-walled carbon nanotubes. J Colloid Interface Sci 286 (2005) 274-279
14. Li F., Zhang B., Dong S., and Wang E. A novel method of electrodepositing highly dispersed nano palladium particles on glassy carbon electrode. Electrochim Acta 42 (1997) 2563-2568
15. 3 catalysts as oxygen cathodes in PEM fuel cells. Electrochem Commun 8 (2006) 406-410
16. Zhou W.J., Li W.Z., Song S.Q., Zhou Z.H., Jiang L.H., Sun G.Q., et al. Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells. J Power Sources 131 (2004) 217-223
17. Pattabiraman R. Electrochemical investigations on carbon supported palladium catalysts. Appl Catal A 153 (1997) 9-20
18. Kiros Y., and Schwartz S. Long-term hydrogen oxidation catalysts in alkaline fuel cells. J Power Sources 87 (2000) 101-105
19. Giacomini M.T., Balasubramanian M., Khalid S., McBreen J., and Ticianelli E.A. Characterization of the activity of palladium-modified polythiophene electrodes for the hydrogen oxidation and oxygen reduction reactions. J Electrochem Soc 150 (2003) A588-A593
20. Moreira J., del Angel P., Ocampo A.L., Sebastian P.J., Montoya J.A., and Castellanos R.H. Synthesis, characterization and application of a Pd/Vulcan and Pd/C catalyst in a PEM fuel cell. Int J Hydro Energy 29 (2004) 915-920
21. Escudero M.J., Hontanon E., Schwartz S., Boutonnet M., and Daza L. Development and performance characterisation of new electrocatalysts for PEMFC. J Power Sources 106 (2002) 206-214
22. Damaskin B.B., and Petrii O.A. Introduction to electrochemical kinetics (1975), Vysshaya shkola, Moscow
23. Gloaguen F., Leger J.-M., and Lamy C. Electrocatalytic oxidation of methanol on platinum nanoparticles electrodeposited onto porous carbon substrates. J Appl Electrochem 27 (1997) 1052-1060
24. 6 on a carbon support. Catal Today 107-108 (2005) 826-830
25. Bockris JO'M, Reddy AKN. Modern electrochemistry, vol. 2. New York: Plenum Press; 1970.