The molecular origin of enhanced toughness in double-network hydrogels: A neutron scattering study

Polymer

Volumn 48, Issue 26, 2007, Pages 7449-7454

  Tominaga, Taiki ^a,b   Tirumala, Vijay R ^a,c   Lin, Eric K ^a   Gong, Jian Ping ^b   Furukawa, Hidemitsu ^b   Osada, Yoshihito ^b   Wu, Wen li ^a  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^b HOKKAIDO UNIVERSITY   (Japan)

^c UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

Hydrogels; Small angle neutron scattering; Solution blends

Indexed keywords

CROSSLINKING; NEUTRON SCATTERING; POLYACRYLATES; RHEOLOGY;

SOLUTION BLENDS; SOLUTION MIXTURES;

HYDROGELS;

CROSS LINKING AGENT; DEFORMATION; HYDROGEL; MOLECULAR STRUCTURE; POLYACRYLAMIDE; POLYMER BLEND; WATER;

EID: 36549007552     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2007.10.016     Document Type: Article

References (29)

1. Haraguchi K., and Takeshita T. Adv Mater 14 (2002) 1121
2. Okumura Y., and Ito K. Adv Mater 13 (2001) 485
3. Haraguchi K., Takeshita T., and Fan S. Macromolecules 35 (2002) 10162
4. Shibayama M., Suda J., Karino T., Okabe S., Takehisa T., and Haraguchi K. Macromolecules 37 (2004) 9606
5. Karino T., Okumura Y., Ito K., and Shibayama M. Macromolecules 37 (2004) 6177
6. Karino T., Okumura Y., Zhao C., Kataoka T., Ito K., and Shibayama M. Macromolecules 38 (2005) 6161
7. Gong J.P., Katsuyama Y., Kurokawa T., and Osada Y. Adv Mater 15 (2003) 1155-1158
8. Kaneko D., Tada T., Kurokawa T., Gong J.P., and Osada Y. Adv Mater 17 (2005) 535-538
9. Nakayama A., Kakugo A., Gong J.P., Osada Y., Takai M., Erata T., et al. Adv Funct Mater 14 (2004) 1124
10. Yasuda K., Gong J.P., Katsuyama Y., Nakayama A., Tanabe Y., Kondo E., et al. Biomaterials 26 (2005) 4468
11. Kwon H.J., and Gong J.P. Curr Opin Colloid Sci 11 (2006) 345
12. Certain equipment, instruments or materials are identified in this paper in order to adequately specify the experimental details. Such identification does not imply recommendation by the National Institute of Standards and Technology nor does it imply the materials are necessarily the best available for the purpose.
13. Shull K.R. J Polym Sci Part B Polym Phys 44 (2006) 3436-3439
14. Okamura K. Europhys Lett 67 (2004) 470-476
15. Tanaka Y., Osada Y., and Gong J.P. Prog Polym Sci 30 (2005) 1-9
16. Webber R.E., Creton C., Brown H.R., and Gong J.P. Macromolecules 40 (2007) 2919
17. Brown H.R. Macromolecules 40 (2007) 3815-3818
18. Jang S.S., Goddard W.A., and Kalani M.Y.S. J Phys Chem B 111 (2007) 1729
19. Glinka C.J., Barker J.G., Hammouda B., Krueger S., Moyer J.J., and Orts W.J. J Appl Crystallogr 31 (1998) 430-445
20. Barker J.G., Glinka C.J., Moyer J.J., Kim M.-H., Drews A.R., and Agamalian M. J Appl Crystallogr 38 (2005) 1004
21. Kline S.R. J Appl Crystallogr 39 (2006) 895
22. Zhou J., Childs R.F., and Mika A.M. J Membr Sci 254 (2005) 89-99
23. Munk P., Aminabhavi T.M., Williams P., and Hoffman D.E. Macromolecules 13 (1980) 871-875
24. Sukhishvili S., Kharlempieva E., and Izumrudov V. Macromolecules 39 (2006) 8873-8881
25. First-principle calculations based on Density Functional Theory indicate that the intermolecular PAMPS and PAAm interactions are possibly stabilized by hydrogen bonding between the sulfonic acid of AMPS and the amide group from AAm.
26. See Fig. 8 and its discussion from. Zaroslov Y.D., Gordeliy V.I., Kuklin A.I., Islamov A.H., Philippova O.E., Khokhlov A.R., et al. Macromolecules 35 (2002) 4466
27. PAAm = 0.696 ± 0.1 cc/g.
28. Kruyt H.R., and Burgers J.M. Second Report on Viscosity and Plasticity (1938), Nordemann Publishing Co., New York p. 81-83
29. Benmouna M., Vilgis T.A., Hakem F., and Negadi A. Macromolecules 24 (1991) 6418