Efficient catalysts for telomerization of butadiene with amines

Tetrahedron Letters

Volumn 48, Issue 52, 2007, Pages 9203-9207

  Grotevendt, Anne ^a   Bartolome, Maribel ^b   Nielsen, David J ^c   Spannenberg, Anke ^a   Jackstell, Ralf ^a   Cavell, Kingsley J ^c   Oro, Luis A ^b   Beller, Matthias ^a  

^a LEIBNIZ INSTITUT FÜR KATALYSE E V AN DER UNIVERSITÄT ROSTOCK   (Germany)

^b UNIVERSITY OF ZARAGOZA   (Spain)

^c CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

1,3 Butadiene; Amines; Carbene; Homogeneous catalysis; Palladium

Indexed keywords

1,3 BUTADIENE; AMINE; CARBENE; HETEROCYCLIC COMPOUND; OCTA 2,7 DIENYLAMINE DERIVATIVE; PALLADIUM; PIPERIDINE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 36448949802     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.10.076     Document Type: Article

References (45)

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45. -1 mol) of 1,3-butadiene was condensed in a separate 75 mL pressure cylinder (mass control). The defined amount of 1,3-butadiene was condensed into the cooled autoclave and the vessel was heated to the desired reaction temperature. After 20 h the autoclave was cooled to room temperature and 5 mL of isooctane as internal standard was added. In general, the yield of telomers was determined by GC using HP 6869A gas chromatograph. The main products were isolated from the reaction mixture via distillation.