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Volumn 149-150, Issue C, 1995, Pages 1-11

Isotope effects in radiative cooling: the Al(C6H6)+ system

Author keywords

Al+ chemistry; Fourier transform ion cyclotron resonance; Ion molecule reactions; Isotope effects; Radiative cooling

Indexed keywords


EID: 3643106098     PISSN: 01681176     EISSN: None     Source Type: Journal    
DOI: 10.1016/0168-1176(95)04223-8     Document Type: Article
Times cited : (30)

References (82)
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  • 40
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    • Catalytic gas-phase oxidation of olefins mediated by Fe(C6H6)+ and a comparison of Fe(L)+ complexes (L = benzene, pyridine, naphthalene)
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    • Stöckigt1    Schwarz2
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    • 2O)) have been reported in J.W. Larson and T.B. McMahon, J. Am. Chem. Soc., 110 (1988) 1087.
  • 56
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    • b is expected to be strongly dependent on the internal energy of the collision complex.
  • 57
    • 0000204247 scopus 로고
    • Using benzene as a neutral, the collision rates are calculated by applying the Langevin theory. For details, see:
    • (1905) Ann. Chim. Phys. , vol.5 , pp. 245
    • Langevin1
  • 62
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    • s symmetrical structure [11].
  • 67
    • 84914613069 scopus 로고    scopus 로고
    • +, see Ref. [15(a)].
  • 68
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    • + by ligand association reactions in the gas phase with rates near the collision limit [8(c),9].
  • 69
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    • Deuterium effects concerning the radiative relaxation of benzene radical cations are reported in
    • (1988) Chem. Phys. Lett. , vol.151 , pp. 128
    • Ahmed1    So2    Dunbar3
  • 70
    • 84914613067 scopus 로고    scopus 로고
    • r values are not outside the experimental uncertainties and should therefore not be overinterpreted. In addition, we do not agree with the error limits of 5% given in Ref. [5(a)] due to the uncertainties associated with precise pressure measurements (about 30%).
  • 71
    • 0001375214 scopus 로고
    • The wavenumbers and assignments of the benzene isotopomers are listed, for example, in
    • (1943) J. Am. Chem. Soc. , vol.65 , pp. 803
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  • 72
    • 84914613066 scopus 로고    scopus 로고
    • r may be fortuitous.
  • 73
    • 84914613065 scopus 로고    scopus 로고
    • 4 s−1 have been reported to be faster by nearly an order of magnitude than expected for a typical hydrocarbon ion.
  • 74
    • 84914613064 scopus 로고    scopus 로고
    • −1. In order to account for the well-known deficiencies of the calculations, the data were scaled by a factor of 0.893.
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    • The procedure has been applied in Ref. [5(a)] and is described in detail by
    • (1975) Spectrochim. Acta , vol.31 A , pp. 797
    • Dunbar1
  • 82
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    • −1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.