Preparation and Physical Properties of MDEA-based Polyurethane Cationomers and their Application to Textile Coatings

Textile Research Journal

Volumn 77, Issue 9, 2007, Pages 710-720

  Tsai, Hsiang Chin ^a   Hong, po da ^a   Yen, Meng Shung ^a  

^a NATIONAL TAIWAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Taiwan)

Author keywords

cationic; physical properties; textile coatings; waterborne polyurethane

Indexed keywords

CONTACT ANGLE; DURABILITY; GLASS TRANSITION; MELTING POINT; POLYCAPROLACTONE; POLYETHYLENES; POLYPROPYLENES; POLYURETHANES; SURFACE TENSION; TENSILE STRENGTH; WASHING; WATERPROOF COATINGS;

CATIONIC AQUEOUS POLYURETHANE COATINGS; POLYDIOLS; POLYOLS; TEXTILE COATINGS; WATER VAPOR PERMEABILITY;

PLASTIC COATINGS;

COATINGS; FABRIC PROPERTY; GLASS TRANSITION TEMPERATURE; MOLECULAR WEIGHT; PHYSICAL PROPERTY; POLYCAPROLACTONE; POLYETHYLENE GLYCOL; POLYURETHANE; THERMAL STABILITY;

EID: 36349014204     PISSN: 00405175     EISSN: None     Source Type: Journal    
DOI: 10.1177/0040517507080544     Document Type: Article

References (25)

1. Yen, M.S., Tsai, H.C., and Hong, P.D., The Physical Properties of Aqueous Cationic-nonionic Polyurethane with Poly (ethylene glycol methyl ether) Side Chain and its Blend with Aqueous Cationic Polyurethane, J. Appl. Polym. Sci. 100, 2963-2974 (2006).
2. Abouzahr, S., Wilkes, G.L., and Ophir, Z., Structure-property Behavior of Segmented Polyether-MDI-butanediol Based Urethane: Effect of Composition Ratio, Polymer 23, 1077-1086 (1982).
3. Jacques, C.H.M., Polymer Alloys, Blend, Block, Crafts, and Interpenetrating Network, in Polymer Science and Technology, Plenum Press, New York, USA (1997).
4. Lorenz, O., and Huck, H., Effect of Solvents on Particle Diameter in Anionic Polyurethane Ionomer Dispersions, Angew. Makromol. Chem. 72, 115-123 (1978).
5. Oertal, G. Nter., and Dieterich, D., Polyurethane Handbook, Hanser Publishers, Munich, New York, pp. 24-28 (1985).
6. Mohanty, S., and Krishnamurt, N., Synthesis and Characterization of Aqueous Cationomeric Polyurethane and their Use as Adhesives, J. Appl. Polym. Sci. 62, 1993-2003 (1996).
7. Frederic, M., Roland, A., and Claude, Q., Flocculation Properties of Some Water-soluble Cationic Copolymers toward Silica Suspensions: A Semi-quantitative Interpretation of the Role of Molecular Weight and Cationicity Through a Patchwork Model, J. Colloid Interface Sci. 97, 120-136 (1984).
8. Teo, L.S., Kuo, J.F., and Chen, C.Y., The Permeation Behaviors of Novel Polyurethane Membranes, in Proceedings of the First Conference on Membrane Science and Technology in Taiwan, Taiwan, pp. 5-13 (2001).
9. Chattopadhyay, B., Srinivasan, K.S.V., Balasubramanian, K., and Ramaswamy, D., Synthesis of Novel Polyurethane Cationomers and their Application in Leather Finishing, J. Am. Leather Chem. Assoc. 84, 48-56 (1989).
10. Sriram, V., Sundar, S., Dattathereyan, A., and Radhakrishnan, G., Synthesis and Characterization of Cationomeric AB Crosslinked Polyurethane Polymers Based on Different Chain Extenders, React. Funct. Polym. 64, 25-32 (2005).
11. Yan, X.W., and Yu, Y.X., A. Novel Synthetic Strategy to Aromatic-diisocyanate-based Waterborne Polyurethane, J. Appl. Polym. Sci. 70, 1621-1626 (1998).
12. Lee, C., and Kim, B.K., Basic Structure Property Behavior of Polyurethane Cationomers, J. Appl. Polym. Sci. 32, 1983-1989 (1994).
13. Chan, W.C., and Chen, S.A., Polyurethane Cationomers. II. Phase Inversion and its Effect on Physical Properties, J. Polym. Sci. B Polym. Phys. 28, 1515-1532 (1990).
14. Ward, R., Urethane Adhesives Based on Caprolactone Polyols, Adhes. Age 13, 10-26 (1970).
15. Kim, B.K., and Lee, Y.M., Aqueous Dispersion of Polyurethane Containing Ionic and Nonionic Hydrophilic Segment, J. Appl. Polym. Sci. 54, 1809-1815 (1994).
16. Kim, B.K., Lee, Y.M., and Lee, J.C., Effect of Soft Segment Length on the Properties of Polyurethane Anionomer Dispersion, Polymer 35, 1095-1099 (1994).
17. Yen, M.S., and Chin, K.S., Effects of a Soft Segment Component on the Physical Properties of Synthesized Waterborne Polyurethanes by using Triblock Ester-ether Copolydiol as the Soft Segment, J. Polym. Res. 5, 125-131 (1998).
18. Yen, M.S., and Chin, K.S., Effects of Mixing Procedure on the Structure and Physical Properties of Ester-ether-type Soft Segment Waterborne Polyurethane, J. Appl. Polym. Sci. 61, 1639-1647 (1996).
19. Yen, M.S., and Chin, K.S., PCL-PEG-PCL Triblock Copolydiol-based Waterborne Polyurethane. I. Effects of the Soft-segment Composition on the Structure and Physical Properties, J. Appl. Polym. Sci. 65, 883-892 (1997).
20. Yen, M.S., and Chin, K.S., PCL-PEG-PCL Triblock Ester-ether Copolydiol-based Waterborne Polyurethane. II. Effect of NCO/OH Mole Ratio and DMPA Content on the Physical Properties, J. Appl. Polym. Sci. 67, 1301-1311 (1998).
21. Frisch, K.C., Hsu, S.L., Xaio, H.X., and Szmant, H.H., Polyurethane Ionomers: Structure-properties Relationships of Polyurethane Ionomers, J. Appl. Polym. Sci. 29, 2467-2479, (1984).
22. Chan, W.C., and Chen, S.A., Polyurethane Cationomers. I. Structure-property Relationship, J. Polym. Sci. B Polym. Phys. 28(9), 1499-1514 (1990).
23. David, D.J., and Staley, H.B., Analytical Chemistry of Polyurethanes, Wiley-Interscience, New York, USA, 16, p. 40 (1969).
24. Hepburn, C., Polyurethane Elastomer, Elsevier Applied Science, London, UK (1991).
25. Ishihara, H., Studies on Segmented Polyurethane-urea Elastomers: Structure and Properties of Segmented Polyurethane-urea Having the Binary Hard Segment Components, J. Macromol. Sci. Phys. 763-782 (1983).